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Merck

483745

Sigma-Aldrich

Sodium

cubes, contains mineral oil, 99.9% trace metals basis

Sinónimos:

Sodium metal

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About This Item

Fórmula empírica (notación de Hill):
Na
Número de CAS:
Peso molecular:
22.99
Número MDL:
Código UNSPSC:
12352300
ID de la sustancia en PubChem:
NACRES:
NA.22
En este momento no podemos mostrarle ni los precios ni la disponibilidad

presión de vapor

1 mmHg ( 440 °C)

Nivel de calidad

Ensayo

99.9% trace metals basis

Formulario

cubes

contiene

mineral oil

idoneidad de la reacción

reagent type: reductant

resistividad

4.69 μΩ-cm, 20°C

bp

883 °C (lit.)

mp

97.8 °C (lit.)

cadena SMILES

[Na]

InChI

1S/Na

Clave InChI

KEAYESYHFKHZAL-UHFFFAOYSA-N

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Descripción general

Sodium serves as a reductant for the difunctionalization of alkenes and alkynes. It is also used in Bouveault-Blanc reduction.[1]

Aplicación

Sodium metal can be used as a reducing agent in reactions such as Birch reduction.[2]

Pictogramas

FlameCorrosion

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Skin Corr. 1B - Water-react 1

Riesgos supl.

Código de clase de almacenamiento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

179.6 °F

Punto de inflamabilidad (°C)

82 °C


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Certificados de análisis (COA)

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The Use of Sodium Metal in the Birch Reduction of Aromatic Compounds1.
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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. This product comes inside a metallic can. What's the correct procedure to open it? what atmosphere is inside? Can it be opened outside a glove box? (the metal can, not the glass container inside)

    1 answer
    1. Please open the metallic canister using a commercially available can opener. The atmosphere inside the canister is air. However, it is important to note that the product (metallic sodium) is stored in mineral oil, which serves to protect it from moisture and air. The metallic canister can be opened outside a glove box due to the presence of mineral oil.

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