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440167

Sigma-Aldrich

(3-Glicidiloxipropil)trimetoxisilano

≥98%

Sinónimos:

3-(2,3-Epoxypropoxi)propiltrimetoxisilano, GLYMO, Éter glicidil 3-(trimetoxisilil)propilo

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About This Item

Fórmula empírica (notación de Hill):
C9H20O5Si
Número de CAS:
2530-83-8
Peso molecular:
236.34
Beilstein/REAXYS Number:
4308125
EC Number:
219-784-2
MDL number:
MFCD00005144
UNSPSC Code:
12352103
PubChem Substance ID:
24867573
NACRES:
NA.23
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Quality Level

200

assay

≥98%

form

liquid

refractive index

n20/D 1.429 (lit.)

bp

120 °C/2 mmHg (lit.)

density

1.07 g/mL at 25 °C (lit.)

SMILES string

CO[Si](CCCOCC1CO1)(OC)OC

InChI

1S/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3

Inchi Key

BPSIOYPQMFLKFR-UHFFFAOYSA-N

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General description

El (3-glicidiloxipropil)trimetoxisilano (GPTMS) es un organosilano bifuncional con tres grupos metoxi en un lado y un anillo epoxi en el otro. Los grupos metoxi se unen bien con sustratos de vidrio creando una matriz tridimensional. El grupo epoxi es reactivo con amidas, alcoholes, tioles y ácidos. El GPTMS es muy reactivo en agua y puede utilizarse como reticulante entre la superficie del sílice y la matriz polimérica.[1][2][3]

Application

El GPTMS se emplea mucho como precursor del sílice. El GPTMS solo con tetraetilortosilicato (TEOS) puede mezclarse con quitosano para utilizarse como relleno de armazones de polímeros para ingeniería de tejido óseo.[4] También puede recubrirse en la superficie de aleación de aluminio para proteger de la corrosión.[5] El GPTMS puede utilizarse para funcionalizar (envolver) natotubos de carbono de pared múltiple (MWCNT), que pueden utilizarse como un refuerzo en los nanocompuestos de matriz epoxi.[2]
El pretratamiento del acero de carbono con 3-(glicidoxipropil)trimetoxisilano potencia la adhesión seca y húmeda mientras que reduce la tasa de desvinculación catódica de un recubrimiento epoxi[6]

Pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H318,H412

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certificados de análisis (COA)

Lot/Batch Number
SDBB1794
SDBB1793
SDBB0475
STBL0642
STBL2731

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Visite la Librería de documentos

Harun, M.K.; et al.
Progress in Organic Coatings, 4, 317-317 (2005)
Journal of Organometallic Chemistry, 625, 208-208 (2001)
Journal of the Chemical Society. Perkin Transactions 1, 729-729 (1997)
Effect of (3-glycidyloxypropyl) trimethoxysilane (GOPS) on the electrical properties of PEDOT: PSS films.
kansson H, et al.
Journal of Polymer Science. Part B, Polymer Physics, 55(10), 814-820 (2017)
Room temperature ionic liquids for epoxy nanocomposite synthesis: Direct dispersion and cure.
Throckmorton JA, et al.
Composites Science and Technology, 86(47), 38-44 (2013)
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Questions

1–9 of 9 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. I would like to know the solvent for GPTMS. What solvents does GPTMS dispersed in?

    1 answer

    1. This product is supplied as a neat or pure liquid with a density of 1.07 g/mL. The minimum purity is 98%. This compound is soluble in water, alcohols, acetone, and most aliphatic esters at normal application levels of 45%.

      Helpful?

  4. I connected  GPTMS synthetically to my lipid(APTES), now my lipid cannot be dissolved in chloroform, ethanol and methanol solutions, which was previously dissolved, what solvent should I use?

    1 answer

    1. The solubility of the GPTMS/APTES sample has not been tested, however decreasing the concentration in chloroform may be useful. Other solvents such as oils (see C8267) or a strong base, such as sodium hydroxide, may also be an option. See the link below to a publication that may be of interest:
      https://pubs.acs.org/doi/10.1021/acssuschemeng.9b06741

      If you have any further issues, please contact https://www.sigmaaldrich.com/techservice, click on "Product Technical Inquiries" under the Products Section, and provide the required information so that a member of the Technical Service team can reach out to assist further. Thank you.

      Helpful?

  5. What is the viscosity of Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO?

    1 answer

    1. This material is a low viscosity liquid with an average value of about 3 centistokes. Please note that this value is not part of our specifications.

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  6. Is Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO, equivalent to Dow's Z-6040?

    1 answer

    1. Yes. This listing is manufactured by Dow Corning Corporation and distributed by Sigma-Aldrich.

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  7. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  8. What can Product 440167, 3-Glycidyloxypropyl)trimethoxysilane GLYMO, be used for?

    1 answer

    1. According to Dow Corning®, 3-GLYCIDOXYPROPYLTRIMETHOXYSILANE can be used as a coupling agent for many thermoset resins with glass or  mineral fillers. Specifically, it has been used as a reinforcement treatment on glass fiber to improve physical properties (especially wet strength) or as  an adhesion promoter to improve the bonding of a polymer coating or adhesive to glass, metals or other polymeric surfaces.

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  9. Where can I find more detailed information about how to use Product 440167. 3-Glycidyloxypropyl)trimethoxysilane, GLYMO, in adhesion/reinforcement applications?

    1 answer

    1. Dow Corning® has published a technical bulletin on this product, which is available by calling Technical Service at 800-231-8327.

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