406139

Chlorodicyclohexylborane

98%

• Sinónimos: Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane
• Fórmula lineal: (C₆H₁₁)₂BCl
• Número de CAS: 36140-19-9
• Peso molecular: 212.57
• MDL number: MFCD00191906
• UNSPSC Code: 12352106
• PubChem Substance ID: 24865357

Propiedades

• assay: 98%
• form: liquid
• reaction suitability: reagent type: reductant
• bp: 100-101 °C/1 mmHg (lit.)
• density: 0.97 g/mL at 25 °C (lit.)
• SMILES string: ClB(C1CCCCC1)C2CCCCC2
• InChI: 1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
• InChI key: PBBOKJIYEZCTEH-UHFFFAOYSA-N

Descripción

Application

A convenient reagent for regio- and stereoselective enolboration of ketones and other carbonyl derivatives.

Reactant for:

• Aldol addition reactions
• Mukaiyama aldol addition
• Microwave assisted ring closing metathesis reactions
• C-alkylation of aromatic aldimines
• Reversible ketone-ketone aldol reactions
• Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

Información de seguridad

• pictograms: GHS02,GHS05
• signalword: Danger
• hcodes: H250,H314
• pcodes: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B
• Storage Class: 4.2 - Pyrophoric and self-heating hazardous materials
• wgk_germany: WGK 3
• flash_point_f: No data available
• flash_point_c: No data available