357537

Pentamethylcyclopentadienyliridium(III) chloride,dimer

96%

• Sinónimos: di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-iridium
• Fórmula empírica (notación de Hill): C₂₀H₃₀Cl₄Ir₂
• Número de CAS: 12354-84-6
• Peso molecular: 796.70
• MDL number: MFCD00075435
• UNSPSC Code: 12161600
• PubChem Substance ID: 24861924
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: 96%
• form: solid
• reaction suitability: core: iridium; reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• greener alternative category: Aligned,
• SMILES string: Cl[Ir]Cl.Cl[Ir]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
• InChI: 1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
• InChI key: JDOHSXHCQARCAW-UHFFFAOYSA-J

Descripción

General description

Pentamethylcyclopentadienyliridium(III) chloride, dimer is utilized as a catalyst in cross-coupling and dimerization reactions.[1]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for greener amine synthesis from amines and alcohols by hydrogen-borrowing. Precursor to cooperative metal-Bronsted acid catalyst for greener reductive amination using hydrogen gas.

Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Development of GSK's reagent guides – embedding sustainability into reagent selection

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)