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346683

Sigma-Aldrich

2-Phenoxyaniline

95%

Sinónimos:

2-Aminophenyl phenyl ether

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About This Item

Fórmula lineal:
C6H5OC6H4NH2
Número de CAS:
2688-84-8
Peso molecular:
185.22
EC Number:
220-254-8
MDL number:
MFCD00035765
UNSPSC Code:
12352100
PubChem Substance ID:
24861427
NACRES:
NA.22

assay

95%

bp

170 °C/18 mmHg (lit.)

mp

47-49 °C (lit.)

SMILES string

Nc1ccccc1Oc2ccccc2

InChI

1S/C12H11NO/c13-11-8-4-5-9-12(11)14-10-6-2-1-3-7-10/h1-9H,13H2

Inchi Key

NMFFUUFPJJOWHK-UHFFFAOYSA-N

Categorías relacionadas

General description

2-Phenoxyaniline forms crystalline 2:1 (host-to-guest) inclusion complexes with β-cyclodextrin.

Application

2-Phenoxyaniline may be used in the preparation of sodium primary amide complex, 2-PhOC6H4NHNa·NMe[(CH2)2NMe2]2. It was used in the preparation of 2-acetoaminodiphenyl ether. It may be used in the preparation of 4-methyl-2-(2-phenoxyphenyl)azo-phenol.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Journal of Pharmaceutical Science and Technology, 1(2), 88-94 (2009)
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Journal of agricultural and food chemistry, 50(1), 29-40 (2002-01-05)
Sensitive and selective enzyme-linked immunosorbent assays (ELISAs) in the immobilized antigen format were developed for fenoxycarb (1), an insect growth regulator (IGR). The parent molecule [ethyl 2-(4-phenoxyphenoxy)ethylcarbamate] was derivatized at several positions to obtain haptens (2-5) that were used to
Susana S Braga et al.
Organic & biomolecular chemistry, 1(5), 873-878 (2003-08-22)
Crystalline 1:1 inclusion complexes with beta-cyclodextrin (beta-CD) and the sodium salt of nimesulide (4-nitro-2-phenoxymethanesulfonanilide), and the sodium salt of the derivative 2-phenoxymethanesulfonanilide, have been prepared by co-precipitation from aqueous solution. The presence of true inclusion complexes was supported by elemental
The first structurally characterised sodium primary amide complex; synthesis and crystal structure of 2-PhOC6H4NHNa? NMe [(CH2) 2NMe2] 2.
Cragg-Hine I, et al.
J. Chem. Soc., Dalton Trans., 19, 2901-2902 (1994)

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