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25190

Sigma-Aldrich

4-Chloro-2-methylphenoxyacetic acid

technical, ≥95.0% (T)

Sinónimos:

4-Chloro-o-tolyloxyacetic acid, MCPA

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About This Item

Fórmula lineal:
ClC6H3(CH3)OCH2CO2H
Número de CAS:
94-74-6
Peso molecular:
200.62
Beilstein:
2051752
Número CE:
202-360-6
Número MDL:
MFCD00004306
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
57648118
NACRES:
NA.22

grado

technical

Ensayo

≥95.0% (T)

Formulario

solid

mp

114-118 °C (lit.)

solubilidad

water: insoluble(lit.)

grupo funcional

carboxylic acid
chloro

cadena SMILES

Cc1cc(Cl)ccc1OCC(O)=O

InChI

1S/C9H9ClO3/c1-6-4-7(10)2-3-8(6)13-5-9(11)12/h2-4H,5H2,1H3,(H,11,12)

Clave InChI

WHKUVVPPKQRRBV-UHFFFAOYSA-N

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Descripción general

4-Chloro-2-methylphenoxyacetic acid (MPCA) is a herbicide. Various MCPA-mineralising bacterial combinations has been tested using a high-throughput microplate radiorespirometric mineralisation assay. Degradation mechanisms of OH and MCPA including molecular form and anionic form have been studied. Rapid and sensitive LC-electrospray tandem mass spectrometry method has been developed for the quantitation of MCPA in water and soil samples.

Palabra de señalización

Danger

Frases de peligro

H302,H315,H318,H410

Clasificaciones de peligro

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 2

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
BCCG4807
BCCG0676
BCCG0675
BCBZ7838
BCBV3948

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Urse S Krüger et al.
Pest management science, 71(2), 257-265 (2014-04-17)
The herbicide 4-chloro-2-methylphenoxyacetic acid (MCPA) is found frequently in Danish groundwater in concentrations exceeding the EU threshold limit of 0.1 µg L(-1) . Groundwater is used for drinking water, and one potential remediation strategy is bioaugmentation using inoculation of sand filters at
Nora Badawi et al.
Environmental pollution (Barking, Essex : 1987), 170, 32-38 (2012-07-06)
Soil suspensions (slurries) are commonly used to estimate the potential of soil microbial communities to mineralize organic contaminants. The preparation of soil slurries disrupts soil structure, however, potentially affecting both the bacterial populations and their protozoan predators. We studied the
O Pozo et al.
Journal of chromatography. A, 923(1-2), 75-85 (2001-08-21)
A rapid and sensitive LC-electrospray tandem mass spectrometry method has been developed for the quantitation of 4-chloro-2-methylphenoxyacetic acid (MCPA) and 4-chloro-2-methylphenol in both water and soil samples. Soil samples were extracted in alkaline media and cleaned-up by solid-phase extraction with
Xiaohua Ren et al.
Chemosphere, 88(1), 39-48 (2012-03-27)
The initial degradation mechanisms of ⁱOH and 4-chloro-2-methylphenoxyacetic acid (MCPA) including molecular form and anionic form are studied at the MPWB1K/6-311+G(3df, 2p)//MPWB1K/6-31+G(d, p) level. Possible reaction pathways of H-atom abstraction and ⁱOH addition are considered in detail. By result comparison
G G Bond et al.
British journal of industrial medicine, 50(4), 340-348 (1993-04-01)
For the purpose of assessing the human carcinogenic potential of the chlorophenoxy herbicides MCPA, MCPP, and 2,4-DP, the relevant epidemiological and toxicological evidence is reviewed. These compounds have not produced tumours in animal studies conducted under current test guidelines, giving
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