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232491

Sigma-Aldrich

5-Methoxyresorcinol

98%

Sinónimos:

3,5-Dihydroxyanisole, Phloroglucinol monomethyl ether

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About This Item

Fórmula lineal:
CH3OC6H3-1,3-(OH)2
Número de CAS:
2174-64-3
Peso molecular:
140.14
Beilstein/REAXYS Number:
1423578
EC Number:
218-532-9
MDL number:
MFCD00002285
UNSPSC Code:
12352100
PubChem Substance ID:
24853905
NACRES:
NA.22

assay

98%

bp

188-189 °C/12 mmHg (lit.)

mp

78-80 °C (lit.)

SMILES string

COc1cc(O)cc(O)c1

InChI

1S/C7H8O3/c1-10-7-3-5(8)2-6(9)4-7/h2-4,8-9H,1H3

InChI key

HDVRLUFGYQYLFJ-UHFFFAOYSA-N

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General description

Kinetics of the aroxyl radical-scavenging action of 5-methoxyresorcinol has been investigated. The kinetics of reaction of 5,7-diisopropyl-tocopheroxyl radical (Toc) with 5-methoxyresorcinol has been measured by stopped-flow spectrophotometer.

Application

5-Methoxyresorcinol was used in synthesis of:
  • isorobustin
  • substituted linear and angular benzofurocoumarins

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Phloroglucinol (anhydrous) European Pharmacopoeia (EP) Reference Standard

Y0000493

Phloroglucinol (anhydrous)

1,3,5-Trimethoxybenzene ReagentPlus®, ≥99%

Sigma-Aldrich

138827

1,3,5-Trimethoxybenzene

Resorcinol ACS reagent, ≥99.0%

Sigma-Aldrich

398047

Resorcinol

Synthesis of linear and angular benzofurocoumarins.
Teran C, et al.
Synthesis, 1997(12), 1384-1386 (1997)
Shuji Mitani et al.
Journal of agricultural and food chemistry, 56(12), 4406-4417 (2008-05-27)
Kinetic study of the aroxyl radical-scavenging action of catechins (epicatechin (EC), epicatechin gallate (ECG), epigallocatechin (EGC), and epigallocatechin gallate (EGCG)) and related compounds (methyl gallate (MG), 4-methylcatechol (MC), and 5-methoxyresorcinol (MR)) has been performed. The second-order rate constant ( k
Kazuo Mukai et al.
Free radical biology & medicine, 38(9), 1243-1256 (2005-04-06)
The reaction rates (k(r)) of 5,7-diisopropyl-tocopheroxyl radical (Toc) with catechins (epicatechin (EC), epicatechin gallate (ECG), epigallocatechin (EGC), epigallocatechin gallate (EGCG)) and related compounds (methyl gallate (MG), 4-methylcatechol (MC), and 5-methoxyresorcinol (MR)) have been measured by stopped-flow spectrophotometer. The k(r) values
Total synthesis of isorobustin.
Barton DHR, et al.
Tetrahedron Letters, 31(51), 7449-7452 (1990)
J U Kreft et al.
European journal of biochemistry, 226(3), 945-951 (1994-12-15)
The previously studied complete methyl transfer sequence of tetrahydrofolate-dependent O-demethylation catalyzed by Holophaga foetida strain TMBS4 extracts was separated into two steps using cobalamins as non-physiological substrates: electrochemically produced cob(I) alamin served as methyl acceptor for phenyl methyl ether demethylation

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