Saltar al contenido
Merck

208302

Sigma-Aldrich

Lead(II) thiocyanate

99.5% trace metals basis

Sinónimos:

Lead sulfocyanide, Lead(II) rhodanide, Plumbous thiocyanate

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización


About This Item

Fórmula lineal:
Pb(SCN)2
Número de CAS:
Peso molecular:
323.36
Beilstein/REAXYS Number:
3687984
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

99.5% trace metals basis

form

powder

mp

190 °C (dec.) (lit.)

solubility

cold water: soluble 200 part(lit.)
water: soluble 50 part (boiling)(lit.)

density

3.82 g/mL at 25 °C (lit.)

SMILES string

N#CS[PbH2]SC#N

InChI

1S/2CHNS.Pb/c2*2-1-3;/h2*3H;/q;;+2/p-2

InChI key

VRNINGUKUJWZTH-UHFFFAOYSA-L

¿Está buscando productos similares? Visita Guía de comparación de productos

Application

Lead (II) thiocyanate can be used:
  • To form a complex with Schiff-base lariat crown ether, N,N′-bis(3-(salicylaldimino)benzyl)-4,13-diaza-18-crown-6.
  • To investigate complexing and fluorescence properties of calixarene bearing two dansyl fluorophores grafted on a large pore mesoporous silica material.
  • As a reagent in the 1,2-dithiocyanation of alkynes in the presence of (dichloroiodo)benzene.
  • As a precursor to synthesize perovskite films for solar cell applications.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

A mesoporous silica functionalized by a covalently bound calixarene-based fluoroionophore for selective optical sensing of mercury (II) in water
M'etivier R, et al.
Journal of Materials Chemistry, 15(27-28), 2965-2973 (2005)
(Dichloroiodo) benzene and lead (II) thiocyanate as an efficient reagent combination for stereoselective 1, 2-dithiocyanation of alkynes
Prakash O, et al.
Tetrahedron Letters, 42(4), 553-555 (2001)
Carlos Platas-Iglesias et al.
Inorganic chemistry, 44(7), 2224-2233 (2005-03-29)
Compounds of formula [Pb(L2)(NCS)2] (1) and [Pb(L4)(SCN)2] (2) (where L2 is the lariat crown ether N,N'-bis(3-aminobenzyl)-4,13-diaza-18-crown-6 and L4 is the Schiff-base lariat crown ether N,N'-bis(3-(salicylaldimino)benzyl)-4,13-diaza-18-crown-6) were isolated and structurally characterized by X-ray diffraction analyses. The X-ray crystal structures of both
A mesoporous silica functionalized by a covalently bound calixarene-based fluoroionophore for selective optical sensing of mercury (II) in water.
Metivier R, et al.
Journal of Materials Chemistry, 15(27-28), 2695-2673 (2005)
O Prakash et al.
The Journal of organic chemistry, 66(6), 2019-2023 (2001-04-13)
The combination reagent (dichloroiodo)benzene and lead(II) thiocyanate in dichloromethane effects oxidation of various enol silyl ethers, ketene silyl acetals, and beta-dicarbonyl compounds, thereby providing an efficient and convenient method for alpha-thiocyanation of carbonyl and beta-dicarbonyl compounds.

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico