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Key Documents

282065

Sigma-Aldrich

Sodium

ACS reagent, dry

Synonym(s):

Sodium metal

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About This Item

Empirical Formula (Hill Notation):
Na
CAS Number:
Molecular Weight:
22.99
EC Number:
MDL number:
UNSPSC Code:
12141806
PubChem Substance ID:
NACRES:
NA.22

grade

ACS reagent

Quality Level

vapor pressure

1 mmHg ( 440 °C)
1 mmHg ( 440 °C)

form

solid

reaction suitability

reagent type: reductant

resistivity

4.69 μΩ-cm, 20°C

bp

883 °C (lit.)

mp

97.8 °C (lit.)

anion traces

chloride (Cl-): ≤0.002%
nitrate (NO3-): ≤0.003%
phosphate (PO43-): ≤5 ppm
sulfate (SO42-): passes test

cation traces

Fe: ≤0.001%
heavy metals (as Pb): ≤5 ppm

SMILES string

[Na]

InChI

1S/Na

InChI key

KEAYESYHFKHZAL-UHFFFAOYSA-N

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Application

Covalent functionalization modifier for carbon nanotubes

Reactant involved in:
  • Synthesis of atrane complexes
  • Zintl phases
  • Sodium dislodging for depolymerization
  • Graphitization of aerogel-like carbons

Packaging

Packaged under nitrogen.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - Water-react 1

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

179.6 °F

Flash Point(C)

82 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Jinfeng Zhang et al.
Inorganic chemistry, 50(19), 9564-9570 (2011-09-10)
A series of sodium and aluminum atrane complexes of Na(3)L(THF)(5) (1), [AlLMe][Na(4)L(THF)(6)] (2), AlL(THF) (3), AlNaLMe(THF)(2) (4), and AlNaLOBn(THF)(2) (5), wherein L = tris(2-oxy-4,6-di-tert-butyl-benzyl)amine, were synthesized and characterized by NMR, X-ray crystallography, and elemental analysis. The trinuclear sodium atrane complex
Jean-Yves Mevellec et al.
Journal of the American Chemical Society, 133(42), 16938-16946 (2011-09-20)
We present a systematic Raman study over a range of excitation energies of arc discharge single-walled carbon nanotubes (SWCNTs) covalently functionalized according to two processes, esterification and reductive alkylation. The SWCNTs are characterized by resonance Raman spectroscopy at each step
H. He, et al.,
Inorganic Chemistry, 50, 8376-8383 (2011)
M. Guzman-Castillo, et al.,
Microporous Mater., 143, 375-382 (2011)
Graphitization of aerogel-like carbons in molten sodium metal
Z. Xu, et al.,
Carbon, 49, 3385-3387 (2011)

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