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28-5700

Sigma-Aldrich

Sulfamic acid

JIS special grade, ≥99.5%

Synonym(s):

Amidosulfonic acid

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About This Item

Linear Formula:
NH2SO3H
CAS Number:
Molecular Weight:
97.09
EC Number:
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:

grade

JIS special grade

Assay

≥99.5%

form

solid

availability

available only in Japan

mp

215-225 °C (dec.) (lit.)

solubility

water: 213 g/L at 20 °C
water: 470 g/L at 80 °C

density

2.151 g/cm3 at 25 °C

SMILES string

NS(O)(=O)=O

InChI

1S/H3NO3S/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

IIACRCGMVDHOTQ-UHFFFAOYSA-N

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Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Amit Saha et al.
Chemical communications (Cambridge, England), 48(71), 8889-8891 (2012-07-21)
Unnatural α-amino acids containing dithiocarbamate side chains were synthesized by a one-pot reaction of in situ generated dithiocarbamate anions with sulfamidates. A wide range of these anions participated in the highly regio- and stereo-selective ring opening of sulfamidates to produce
Na Zhang et al.
The Journal of organic chemistry, 77(14), 5956-5964 (2012-06-21)
The efficiency of arylboron-based nucleophiles, boronic acid, potassium trifluoroborate, neopentylglycolboronate, and pinacol boronate in nickel-catalyzed Suzuki-Miyaura cross-coupling reactions with the two C-O electrophiles, mesylates, and sulfamates was compared. Arylboronic acid is the most reactive and most atom-economic of the four
Derek J Langeslay et al.
Analytical chemistry, 83(20), 8006-8010 (2011-09-15)
Sulfamate (NHSO(3)(-)) groups are critically important structural elements of the glycosaminoglycans heparin and heparan sulfate (HS). Experimental conditions are presented for detection of the sulfamate (1)H NMR resonances in aqueous solution. NMR spectra reported for N-sulfoglucosamine (GlcNS) and the synthetic
Daniel Can et al.
Angewandte Chemie (International ed. in English), 51(14), 3354-3357 (2012-02-22)
Enhanced receptor selectivity: carbonic anhydrase inhibitors are relevant for both cancer diagnosis and therapy. Combining non-radioactive Re compounds with their radioactive (99m)Tc homologs enables the use of identical molecules for therapy and imaging (theragnostic). The syntheses and in vitro evaluation
Toolika Agrawal et al.
Organic letters, 15(1), 96-99 (2012-12-19)
The iron-catalyzed cross-coupling of aryl sulfamates and tosylates has been achieved with primary and secondary alkyl Grignards. This study of iron-catalyzed cross-coupling reactions also examines the isomerization and β-hydride elimination problems that are associated with the use of isopropyl nucleophiles.

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