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1.03170

Supelco

Eriochrome black T (C.I. 14645)

metal indicator, ACS, Reag. Ph Eur

Synonym(s):

Eriochrome black T (C.I. 14645), Chrome black T, 2-Hydroxy-1-(1-hydroxy-2-naphthylazo)-6-nitronaphthalene-4-sulfonic acid sodium salt

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About This Item

Empirical Formula (Hill Notation):
C20H12N3NaO7S
CAS Number:
Molecular Weight:
461.38
MDL number:
UNSPSC Code:
12352107
EC Index Number:
217-250-3
NACRES:
NB.21
Pricing and availability is not currently available.

Product Name

Eriochrome black T (C.I. 14645), indicator for complexometry ACS,Reag. Ph Eur

grade

ACS reagent

Quality Level

Agency

reag. Ph. Eur.

form

powder

potency

17590 mg/kg LD50, oral (Rat)

loss

≤7% loss on drying, 110°C

color

black to dark brown

pH

3.7 (20 °C, 10 g/L in H2O)

solubility

50 g/L

bulk density

400‑600 kg/m3

λmax

612-616 nm (buffer pH 10.0)

storage temp.

15-25°C

SMILES string

[Na+].[S](=O)(=O)(O)C1=CC(=O)\C(=N/Nc3c(c4c(cc3)cccc4)[O-])\c2c1cc(cc2)[N+](=O)[O-]

InChI

1S/C20H13N3O7S.Na/c24-17-10-18(31(28,29)30)15-9-12(23(26)27)6-7-14(15)19(17)22-21-16-8-5-11-3-1-2-4-13(11)20(16)25;/h1-10,21,25H,(H,28,29,30);/q;+1/p-1/b22-19-;

InChI key

JHUJLRKQZAPSDP-GXTSIBQPSA-M

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Linkage

Replaces: EX0100-5; EX0100

Analysis Note

Identity (UV/VIS-Spectrum): passes test
Appearance: Black to dark brown-black fine powder, eventually with granular parts
Clarity of solution: passes test
Absorption maximum λmax. (buffer pH 10.0): 612 - 616 nm
Spec. Absorptivity A 1%/1cm (λmax; 0.02 g/l; buffer pH 10.0; calc. on dried substance): 400 - 510
Loss on drying (110 °C): ≤ 7 %
Suitability as indicator (for complexometric titration, ACS): passes test
Suitability as indicator (Reag. Ph Eur): passes test

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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