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769495

Sigma-Aldrich

Cobalt(II) chloride hexahydrate

≥97%

Synonym(s):

Cobaltous chloride hexahydrate

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About This Item

Linear Formula:
CoCl2 · 6H2O
CAS Number:
Molecular Weight:
237.93
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
form:
solid
Pricing and availability is not currently available.

vapor pressure

40 mmHg ( 0 °C)

Quality Level

Assay

≥97%
97.0-102.0% (KT)

form

solid

anion traces

nitrate (NO3-): ≤0.01%
sulfate (SO42-): ≤0.007%

cation traces

Fe: ≤0.005%
Ni: ≤0.15%
Pb: ≤0.002%
Zn: ≤0.05%

SMILES string

O.O.O.O.O.O.Cl[Co]Cl

InChI

1S/2ClH.Co.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

InChI key

GFHNAMRJFCEERV-UHFFFAOYSA-L

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1 of 4

This Item
25559931277202185
assay

≥97%, 97.0-102.0% (KT)

assay

98%, 98.0-102.0% (ACS specification)

assay

98-102%

assay

-

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

anion traces

nitrate (NO3-): ≤0.01%, sulfate (SO42-): ≤0.007%

anion traces

nitrate (NO3-): ≤0.01%, sulfate (SO42-): ≤0.01%

anion traces

nitrate (NO3-): ≤100 mg/kg, sulfate (SO42-): ≤50 mg/kg

anion traces

-

cation traces

Ni: ≤0.15%, Zn: ≤0.05%, Pb: ≤0.002%, Fe: ≤0.005%

cation traces

Ca: ≤0.005%, Cu: ≤0.002%, Fe: ≤0.005%, K: ≤0.01%, Mg: ≤0.005%, Na: ≤0.05%, Ni: ≤0.1%, Zn: ≤0.03%

cation traces

Ca: ≤50 mg/kg, Cu: ≤20 mg/kg, Fe: ≤50 mg/kg, K: ≤50 mg/kg, Mg: ≤10 mg/kg, Mn: ≤50 mg/kg, Na: ≤100 mg/kg, Ni: ≤500 mg/kg, Pb: ≤5 mg/kg, Zn: ≤25 mg/kg

cation traces

-

vapor pressure

40 mmHg ( 0 °C)

vapor pressure

40 mmHg ( 0 °C)

vapor pressure

40 mmHg ( 0 °C)

vapor pressure

40 mmHg ( 0 °C)

General description

Cobalt(II) chloride hexahydrate, a hydrated form of cobalt chloride, is employed in electroplating and catalyst preparation. It serves as a precursor for synthesizing electrode materials for lithium-ion batteries and acts as a catalyst in a range of organic reactions, including acetylation, tosylation of alcohols, and condensation reactions.

Application

Cobalt(II) chloride hexahydrate can be used as:      
  • An additive to the electron transport layer (ETL) in perovskite solar cells to improve their performance, particularly by reducing energy losses and increasing the open-circuit voltage.      
  • A cobalt source for doping ZnO nanostructures. The incorporation of cobalt ions into the ZnO matrix is crucial for modifying its electronic and optical properties.      
  • A precursor to modify cobalt metal-organic framework (Co-MOF) derived carbon microspheres for application as anode materials in lithium-ion batteries.

Analysis Note

Substances not precipitated by ammonium sulfide (as sulphates) ≤ 0.3 %

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Electroplating and characterization of cobalt-nickel-iron and nickel-iron for magnetic microsystems applications
Rasmussen, FE., et al.
Sensors and actuators A, Physical, 92, 242-248 (2001)
Hyeohn Kim et al.
ACS nano, 15(1), 979-988 (2020-12-18)
Chiral inorganic nanomaterials have revealed opportunities in various fields owing to their strong light-matter interactions. In particular, chiral metal oxide nanomaterials that can control light and biochemical reactions have been highlighted due to their catalytic activity and biocompatibility. In this
Sebastian Klemenz et al.
ChemSusChem, 11(18), 3150-3156 (2018-07-27)
High-performance catalysts for the oxygen-evolution reaction in water electrolysis are usually based on expensive and rare elements. Herein, mixed-metal borides are shown to be competitive with established electrocatalysts like noble metal oxides and other transition-metal(oxide)-based catalysts. Iron incorporation into nanoscale
Excellent lithium ion storage property of porous MnCo2O4 nanorods
Zeng, P., et al.
Royal Society of Chemistry Advances, 6, 23074-23084 (2016)
One-step synthesis of cobalt and nitrogen co-doped carbon nanotubes and their catalytic activity for the oxygen reduction reaction
Fu, S., et al.
Journal of Material Chemistry A, 3, 12718-12722 (2015)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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