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440752

Sigma-Aldrich

Polycaprolactone

greener alternative

average Mw ~14,000, average Mn ~10,000 by GPC

Synonym(s):

2-Oxepanone homopolymer, 6-Caprolactone polymer

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About This Item

Linear Formula:
(C6H10O2)n
UNSPSC Code:
12162002
NACRES:
NA.23
Pricing and availability is not currently available.

form

flakes or chunk(s)

mol wt

average Mn ~10,000 by GPC
average Mw ~14,000

greener alternative product characteristics

Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

viscosity

400-1000 mPa.s, 50 wt. % in xylene

mp

60 °C (lit.)

transition temp

Tg −60 °C

density

1.146 g/mL at 25 °C

greener alternative category

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General description

Polycaprolactone is a α,ω-dihydroxy functional polymer.
We are committed to bringing you Greener Alternative Products, which belongs to one of the four categories of greener alternatives. This is an enabling product that belongs to a family of high-performance bio-based polymers that are essential for developing efficient, low-cost, and environmentally friendly renewable energy solutions. Click here for more information.

Application

Polycaprolactone may find use as an extrusion aid, die lubricant, mold release, pigment and filler dispersion aid and polyester segments in urethanes and block polyesters.

Features and Benefits

Biodegradable polymer
Non-toxic, biodegradable in soil, broad miscibility, mechanical compatibility with many polymers and good adhesion to a broad spectrum of substrates.

Physical form

α,ω-dihydroxy functional polymer.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

>230.0 °F

Flash Point(C)

> 110 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number

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Kyungjin Park et al.
Scientific reports, 7(1), 13359-13359 (2017-10-19)
Optical resolution photoacoustic microscopy (OR-PAM) is a non-invasive, label-free method of in vivo imaging with microscopic resolution and high optical contrast. Based on intrinsic contrasts, OR-PAM has expanded to include in vivo vessel imaging, flow cytometry, physiological parameter analysis, and
Jack R T Darby et al.
The Journal of physiology, 597(20), 5063-5077 (2019-09-05)
Substrate restriction during critical developmental windows of gestation programmes offspring for a predisposition towards cardiovascular disease in adult life. This study aimed to determine the effect of maternal resveratrol (RSV) treatment in an animal model in which chronic fetal catheterisation
Zhaodong Wang et al.
Carbohydrate polymers, 94(1), 505-510 (2013-04-03)
An ionic liquid, 1-ethyl-3-methylimidazolium acetate (EMIMAc), was synthesized and employed as a homogeneous and green reaction media to prepare chitosan-graft-polycaprolactone (CS-g-PCL) via ring-opening polymerization, using stannous octoate (Sn(Oct)2) as a catalyst. The structures and compositions of copolymers could be facilely
Jixin Xue et al.
Biomaterials, 34(11), 2624-2631 (2013-01-29)
Tissue engineering approach continuously requires for emerging strategies to improve the efficacy in repairing and regeneration of tissue defects. Previously, we developed a sandwich model strategy for cartilage engineering, using the combination of acellular cartilage sheets (ACSs) and chondrocytes. However
Kalaipriya Madhaiyan et al.
International journal of pharmaceutics, 444(1-2), 70-76 (2013-02-02)
Biocompatible PCL polymer nanofiber mediated sustained release of hydrophilic drug and applicability as transdermal delivery system is attempted. This new attempt to investigate water soluble vitamin delivery with hydrophobic polymer nanofiber sustained the release of the vitamin and the method

Articles

In the past two decades, tissue engineering and regenerative medicine have become important interdisciplinary fields that span biology, chemistry, engineering, and medicine.

Innovations in polymer technology have had a significant impact on the advancement of novel drug delivery systems.

Questions

1–5 of 5 Questions  
  1. What are the end groups of this PCL?

    1 answer
    1. This material is considered a diol and contains a hydroxyl group at each end of the polymer chain.

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  4. What are the associated GHS hazards statements for PCL?

    1 answer
    1. As mentioned in Section 2 of the Safety Data Sheet, there are no GHS Label elements because this product is not classified as a hazardous substance or mixture.

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  5. What is the storage specifications for this chemical?

    1 answer
    1. This product may be stored at room temperature. For products with no specified storage temperature given on the label or product page, ambient storage may be assumed. Products that require controlled temperature storage, such as refrigeration or freezer conditions, storage temperatures are published on the product label, Certificate of Analysis, and the Safety Data Sheet (SDS).

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