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Sigma-Aldrich

Poly(diallyldimethylammonium chloride) solution

average Mw 400,000-500,000 (high molecular weight), 20 wt. % in H2O

Synonym(s):

PDADMAC

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About This Item

Linear Formula:
(C8H16ClN)n
CAS Number:
MDL number:
UNSPSC Code:
12162002
NACRES:
NA.23

form

viscous liquid

Quality Level

mol wt

average Mw 400,000-500,000 (high molecular weight)

concentration

20 wt. % in H2O

refractive index

n20/D 1.37

viscosity

600-900 cP(25 °C)

density

1.04 g/mL at 25 °C

InChI

1S/C8H16N.ClH/c1-5-7-9(3,4)8-6-2;/h5-6H,1-2,7-8H2,3-4H3;1H/q+1;/p-1

InChI key

GQOKIYDTHHZSCJ-UHFFFAOYSA-M

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General description

Poly(diallyldimethylammonium chloride) is a water-soluble cationic polymer that can be prepared from diallyl dimethyl ammonium chloride via free radical polymerization.

It is a positively charged polyelectrolyte that finds application in various fields such as paper manufacturing, the mining industry, water treatment, protein immobilization, separation of biomolecules, removal of bacteria, flocculation of silica and latex particles, and nanocapsule shell formation.

Application

  • Influence of ionic strength on poly(diallyldimethylammonium chloride) macromolecule conformations in electrolyte solutions: Studies the effect of ionic strength on the conformation of PDADMAC in electrolyte solutions. (Z Adamczyk et al., 2014).
  • Comparison of permeability of poly(allylamine hydrochloride) and poly(diallyldimethylammonium chloride)/poly(4-styrenesulfonate) multilayer films: Examines permeability differences in multilayer films of PAH and PDADMAC/PSS. (M Elżbieciak-Wodka et al., 2015).
  • Effect of small molecules on the phase behavior and coacervation of aqueous solutions of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrene sulfonate): Investigates the impact of small molecules on the coacervation of PDADMAC and PSS. (S Huang et al., 2018).
  • Dynamic surface elasticity of mixed poly(diallyldimethylammonium chloride)/sodium dodecyl sulfate/NaCl solutions: Analyzes the dynamic dilational surface elasticity of PDADMAC/SDS/NaCl mixtures. (VV Lyadinskaya et al., 2014).

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Shear thickening behavior of dilute poly(diallyl dimethyl ammonium chloride) aqueous solutions
Wen-Hong Liu, et al.
Polymer, 48, 4152-4165 (2007)
John Crosby et al.
Chemical communications (Cambridge, England), 48(97), 11832-11834 (2012-10-27)
Compartmentalization of the minimal complex of actinorhodin polyketide synthase in coacervate liquid droplets produces enhanced yields of shunt polyketides under conditions of low and high ionic strength.
Urszula Bazylińska et al.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 47(2), 406-420 (2012-07-17)
There is great clinical interest in developing novel nanocarriers for hydrophobic cyanine dyes used as photosensitizing agents in photodynamic therapy (PDT). In the present study we have employed nanoemulsion-templated oil-core multilayer nanocapsules as robust nanocarriers for a cyanine-type photosensitizer IR-786.
Cédric Amorosi et al.
Colloids and surfaces. B, Biointerfaces, 97, 124-131 (2012-05-23)
Compact and linearly growing polyelectrolyte multilayer films have been used to suppress desorption of drugs, nanoparticles or proteins from underlying polyelectrolyte multilayer films as well as to significantly change their mechanical properties. The polyelectrolyte based capping layers are however cumbersome
Lulu Han et al.
Journal of the Royal Society, Interface, 9(77), 3455-3468 (2012-08-17)
The cell migration plays a crucial role in a variety of physiological and pathological processes and can be regulated by the cell-substrate interactions. We found previously that the poly(sodium 4-styrenesulphonate) (PSS)/poly(diallyldimethylammonium) chloride (PDADMAC) multilayers post-treated in 1-5 M NaCl solutions

Articles

We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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