109576
1,1′-Dimethylferrocene
95%
Synonym(s):
Bis(methylcyclopentadienyl)iron
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About This Item
Empirical Formula (Hill Notation):
C12H14Fe
CAS Number:
Molecular Weight:
214.08
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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Assay
95%
form
solid
reaction suitability
core: iron
reagent type: catalyst
mp
37-40 °C (lit.)
SMILES string
[Fe].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2
InChI
1S/2C6H7.Fe/c2*1-6-4-2-3-5-6;/h2*2-5H,1H3;
InChI key
GJFIEPAJMYPAGC-UHFFFAOYSA-N
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
226.4 °F - closed cup
Flash Point(C)
108.00 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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M Wenzel et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 43(11-12), 963-966 (1988-11-01)
The relative stabilities of different ferricinium cations were studied in buffer or serum-containing solution and in vivo and compared with their cytostatic effects in cultures of Yoshida ascites tumor cells. Although the ferricinium cation itself was the most unstable cation
K B Male et al.
Applied biochemistry and biotechnology, 44(1), 91-100 (1994-01-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (Hp-beta-CyD), a cyclic and nonreducing oligosaccharide was used to enclose a hydrophobic guest molecule 1,1'-dimethylferrocene (DMF) to form a water-soluble yellow complex. At high concentrations (300 mM), Hp-beta-CyD enclosed up to 100 mM DMF. The yellow complex was
J H Luong et al.
Analytical biochemistry, 212(1), 269-276 (1993-07-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (hp-beta-CyD), a cyclic and nonreducing oligosaccharide, was used to enclose the hydrophobic guest molecules ferrocene (FeCp2) and 1,1'-dimethylferrocene (DMFeCp2) to form a water-soluble complex. At high concentrations (300 mM), hp-beta-CyD enclosed up to 100 mM FeCp2 or DMFeCp2.
J H Luong et al.
Journal of molecular recognition : JMR, 8(1-2), 132-138 (1995-01-01)
Inclusion complexes of 1,1'-dimethylferrocene (DMFe) with alpha-, 2-hydroxypropyl-beta- or gamma-cyclodextrins were formed in aqueous systems. For the first time, the interacting DMFe-cyclodextrin systems have been characterized using cyclic voltammetry which enabled the estimation of the complexation order, the formation constant
D J Claremont et al.
Diabetologia, 29(11), 817-821 (1986-11-01)
Miniature, amperometric glucose sensors were constructed using entrapped 1,1'-dimethylferrocene to mediate electron transfer between immobilised glucose oxidase and a carbon base electrode. Electrodes were calibrated in buffered glucose solutions and then implanted in the subcutaneous tissue of anaesthetised, non-diabetic pigs.
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