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930164

Sigma-Aldrich

Lithium hexafluorophosphate solution

in ethylene carbonate and ethyl methyl carbonate, 1.2 M LiPF6 in EC/EMC=30/70 (w/w), battery grade

Synonym(s):

1.2 M LiPF6 in EC/EMC=30/70 (w/w)

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About This Item

Linear Formula:
LiPF6
MDL number:
MFCD00011096
UNSPSC Code:
26111700
NACRES:
NA.21

grade

battery grade

Quality Level

100

SMILES string

F[P-](F)(F)(F)(F)F.[Li+]

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChI key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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Application

Lithium hexafluorophosphate solution in ethylene carbonate and ethyl methyl carbonate is a class of electrolytic solution that can be used in lithium-ion batteries. A high demand for Lithium-Ion Battery with higher energy, powder density, and density requires a new electrolyte formulation to enhance the properties. This product is the “2nd generation electrolyte”, which is a naming system used by the United States Department of Energy (DOE) in the Advanced Technology Development Program for advanced lithium-ion battery systems. These materials enable the formation of greener and sustainable batteries for electrical energy storage.

Signal Word

Danger

Hazard Statements

H226,H302,H314,H372,H373

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A - STOT RE 1 Inhalation - STOT RE 2 Oral

Target Organs

Bone,Teeth, Kidney

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

80.6 °F

Flash Point(C)

27.0 °C

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Challenges for Rechargeable Li Batteries.
Goodenough J B, et al.
Chemistry of Materials, 22, 587-603 (2010)
Fluorinated electrolytes for Li-ion battery: An FEC-based electrolyte for high voltage LiNi0.5Mn1.5O4/graphite couple.
Hu Libo, et al.
Electrochemical Communications, 35, 76-79 (2013)
Electrochemical investigation of carbonate-based electrolytes for high voltage lithium-ion cells.
Hu Libo, et al.
Journal of Power Sources, 236, 175-180 (2013)
Fluorinated electrolytes for 5 V lithium-ion battery chemistry.
Zhang Z, et al.
Energy & Environmental Science, 6, 1806-1810 (2013)
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
Kang Xu
Chemical reviews, 104(10), 4303-4417 (2005-01-27)
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