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700703

Sigma-Aldrich

N-tert-Butyl-N-(2-methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylamine

Synonym(s):

2,2,5-Trimethyl-3-(1-phenylethoxy)-4-phenyl-3-azahexane, Alkoxyamine NMP initiator

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About This Item

Empirical Formula (Hill Notation):
C22H31NO
CAS Number:
227000-59-1
Molecular Weight:
325.49
MDL number:
MFCD12546017
UNSPSC Code:
12162002
PubChem Substance ID:
329762224
NACRES:
NA.23

form

liquid

refractive index

n20/D 1.536

density

0.968 g/mL at 25 °C

storage temp.

−20°C

SMILES string

CC(C)C(N(OC(C)c1ccccc1)C(C)(C)C)c2ccccc2

InChI

1S/C22H31NO/c1-17(2)21(20-15-11-8-12-16-20)23(22(4,5)6)24-18(3)19-13-9-7-10-14-19/h7-18,21H,1-6H3

InChI key

FPFRTDOMIFBPBZ-UHFFFAOYSA-N

Related Categories

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Application

Block Copolymer Synthesis Using a Commercially Available NMP Inititator

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Benoit, D., Chaplinski, V., Braslau, R., Hawker, C.J.
Journal of the American Chemical Society, 121, 3904-3904 (1999)

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Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

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Polymerizing via ATRP

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Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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