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521892

Sigma-Aldrich

6-Methoxy-2-naphthaleneboronic acid

≥95%

Synonym(s):

6-Methoxy-2-naphthalenylboronic acid, 6-Methoxy-2-naphthylboronic acid, 6-Methoxynaphthalene-2-boronic acid

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About This Item

Linear Formula:
C10H6OCH3B(OH)2
CAS Number:
156641-98-4
Molecular Weight:
202.01
MDL number:
MFCD03093087
UNSPSC Code:
12352103
PubChem Substance ID:
24874233

Assay

≥95%

mp

>295 °C (lit.)

SMILES string

COc1ccc2cc(ccc2c1)B(O)O

InChI

1S/C11H11BO3/c1-15-11-5-3-8-6-10(12(13)14)4-2-9(8)7-11/h2-7,13-14H,1H3

InChI key

GZFAVYWCPSMLCM-UHFFFAOYSA-N

General description

Contains varying amounts of anhydride.

Application

Reactant for:
  • Suzuki-Miyaura coupling
  • Enantioselective a-arylation of carbonyls via copper-bisoxazoline catalysis
  • Enantioselective synthesis of aryl ketones
  • Copper-catalyzed trifluoromethylation
  • Rhodium-catalyzed oxidative coupling with alkynes

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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