405701

Allyl P,P-diethylphosphonoacetate

97%

• Synonym(s): Phosphonoacetic acid P,P-diethyl allyl ester
• Linear Formula: (C₂H₅O)₂P(O)CH₂COOCH₂CH=CH₂
• CAS Number: 113187-28-3
• Molecular Weight: 236.20
• Beilstein: 1788582
• MDL number: MFCD00191710
• UNSPSC Code: 12352108
• PubChem Substance ID: 24865325
• NACRES: NA.22

Properties

• Assay: 97%
• form: liquid
• reaction suitability: reaction type: C-C Bond Formation
• refractive index: n20/D 1.445 (lit.)
• bp: 157-158 °C/10 mmHg (lit.)
• density: 1.12 g/mL at 25 °C (lit.)
• SMILES string: CCOP(=O)(CC(=O)OCC=C)OCC
• InChI: 1S/C9H17O5P/c1-4-7-12-9(10)8-15(11,13-5-2)14-6-3/h4H,1,5-8H2,2-3H3
• InChI key: USZLAMOPIWNLPH-UHFFFAOYSA-N

Description

Application

Reactant for:

• Horner-Wadsworth-Emmons reaction
• Preparation of phosphonate-functionalized cyclopentenones via regioselective Pauson-Khand processes
• Preparation of salicylihalamide analog saliphenylhalamide as potential vacuolar ATPase inhibitors and anticancer agents
• Solid-phase synthesis of olefin-containing peptides via Horner-Emmons reaction as inhibitors of HTLV-1 protease
• Synthesis of fluorescent poly(aromatic amide) dendrimers

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H319
• Precautionary Statements: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 230.0 °F - closed cup
• Flash Point(C): 110 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves