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Sigma-Aldrich

Poly(sodium 4-styrenesulfonate)

average Mw ~70,000

Synonym(s):

PSS, Poly(4-styrenesulfonic acid) sodium salt

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About This Item

Linear Formula:
(C8H7NaO3S)n
CAS Number:
MDL number:
UNSPSC Code:
12162002
NACRES:
NA.23

form

powder or solid

Quality Level

mol wt

average Mw ~70,000

viscosity

15-55 cP, 20 %(25 °C, Brookfield)(lit.)

mp

460 °C (dec.)

solubility

water and lower glycols: soluble

density

0.801 g/mL at 25 °C (lit.)

InChI

1S/C8H8O3S/c1-2-7-3-5-8(6-4-7)12(9,10)11/h2-6H,1H2,(H,9,10,11)

InChI key

MAGFQRLKWCCTQJ-UHFFFAOYSA-N

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General description

Poly (sodium 4-styrenesulfonate) (PSS) a cation exchange polyelectrolyte. PSS may be used to produce mechanically stable and very reproducible coatings.

Application

Reduction of graphite oxide in the presence of PSS has been reported for the synthesis of polymer-coated graphitic nanoplatelets. Interaction of PSS with metal ions has been studied. PSS combined with Nafion has been reported to be used a mixed coating of Bismuth film electrodes.

Features and Benefits

Anionic polyelectrolyte.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Poly (sodium 4?styrenesulfonate)?metal ion interactions
Rivas BL, et al.
Journal of Applied Polymer Science, 70(2), 219-225 (1998)
Nafion/Poly (sodium 4?styrenesulfonate) Mixed Coating Modified Bismuth Film Electrode for the Determination of Trace Metals by Anodic Stripping Voltammetry.
Jia J, et al.
Electroanalysis, 19(17), 1845-1849 (2007)
Polyelectrolyte Multilayer Films and Membrane Functionalization
Bruening ML and Adusumilli M
Material Matters, 6(3) null
Anton Gurkov et al.
PloS one, 12(10), e0186548-e0186548 (2017-10-19)
In vivo physiological measurement is a major challenge in modern science and technology, as is environment conservation at the global scale. Proper toxicological testing of widely produced mixtures of chemicals is a necessary step in the development of new products
Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly (sodium 4-styrenesulfonate).
Stankovich S, et al
Journal of Materials Chemistry, 16(2), 155-158 (2006)

Articles

Professor Rivnay (Northwestern University, USA) discusses using organic mixed conductors as an alternative to efficiently bridge the ionic world of biology with contemporary microelectronics.

We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.

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