179043
Borane N,N-diethylaniline complex
Synonym(s):
(N,N-Diethylaniline)trihydroboron, Diethylphenylamine-borane, NSC 239123
About This Item
Recommended Products
form
liquid
Quality Level
reaction suitability
reagent type: reductant
mp
−30-−27 °C (lit.)
density
0.917 g/mL at 25 °C (lit.)
SMILES string
B.CCN(CC)c1ccccc1
InChI
1S/C10H15N.BH3/c1-3-11(4-2)10-8-6-5-7-9-10;/h5-9H,3-4H2,1-2H3;1H3
InChI key
YPWBYWNNJVSNPQ-UHFFFAOYSA-N
Related Categories
Application
- Diastereoselective reduction of prochiral enone intermediates
- Borylation of aryl halides
- Reductions of ketones, acids, esters, amides, and nitriles
- Investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones
Reactant for synthesis of:
- Chromanol derivatives as CETP inhibitors for the treatment of cardiovascular disease
- Allylic alcohols via enantioselective reductions
- Pinacolboranes for one-pot synthesis of unsymmetrical biaryls
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 2 - Water-react 2
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
69.8 °F - closed cup
Flash Point(C)
21 °C - closed cup
Personal Protective Equipment
Certificates of Analysis (COA)
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