363685
Silver carbonate on Celite®
extent of labeling: ~50 wt. % loading
Synonym(s):
Fetizon′s reagent
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About This Item
Linear Formula:
Ag2CO3
CAS Number:
Molecular Weight:
275.75
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
form
powder and chunks
Quality Level
concentration
45-60 wt. % (by KSCN, titration)
extent of labeling
~50 wt. % loading
SMILES string
[Ag]OC(=O)O[Ag]
InChI
1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
InChI key
KQTXIZHBFFWWFW-UHFFFAOYSA-L
Application
Employed in the silver ion induced preparation of α-keto acetals and α,α-dialkoxy imines. Catalyzes the generation of stereospecific unsaturated aldehydes from vinylic halides and primary amines.
Legal Information
Celite is a registered trademark of Imerys Minerals California, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Synthesis, 427-427 (1994)
Tetrahedron Letters, 31, 6641-6641 (1990)
Gregory L Hamilton et al.
Journal of the American Chemical Society, 130(45), 14984-14986 (2008-10-22)
Reactions proceeding through cationic intermediates that lack a Lewis or Brønsted basic site present a challenge for traditional asymmetric catalysis based on chiral metals or organocatalysts. We present an enantioselective ring opening of tetrasubstituted meso-aziridinium ions with alcohol nucleophiles proceeding
V Pacheco-Fowler et al.
The Journal of hospital infection, 57(2), 170-174 (2004-06-09)
The effect of endotracheal tubes (ETTs) impregnated with chlorhexidine (CHX) and silver carbonate (antiseptic ETTs) against Staphylococcus aureus, methicillin-resistant S. aureus (MRSA), Pseudomonas aeruginosa, Acinetobacter baumannii, and Enterobacter aerogenes [organisms associated with ventilator-associated pneumonia (VAP)], was evaluated in a laboratory
Palladium-catalyzed decarboxylative C-H bond arylation of thiophenes.
Peng Hu et al.
Angewandte Chemie (International ed. in English), 51(1), 227-231 (2011-11-17)
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