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8.01081

Sigma-Aldrich

Aluminium chloride

anhydrous powder sublimed for synthesis

Synonym(s):

Aluminium chloride, Hydrochloric acid aluminium salt anhydrous, Trichloroaluminum

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About This Item

Empirical Formula (Hill Notation):
AlCl3
CAS Number:
7446-70-0
Molecular Weight:
133.34
MDL number:
MFCD00003422
UNSPSC Code:
12352302
EC Index Number:
231-208-1
NACRES:
NA.22

vapor pressure

1 hPa ( 20 °C)

Quality Level

200

form

powder

potency

3450 mg/kg LD50, oral (Rat)
>2000 mg/kg LD50, skin (Rabbit)

pH

2.4 (20 °C, 100 g/L in H2O)

mp

180-181 °C (sublimed)

solubility

450 g/L (decomposition)

density

1.31 g/cm3 at 200 °C (liquid)

bulk density

1200 kg/m3

storage temp.

2-30°C

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI key

VSCWAEJMTAWNJL-UHFFFAOYSA-K

General description

Aluminum chloride and Aluminum hydroxide are used for the staining of Mucicarmine.

Application

Aluminium chloride (AlCl3) can be used as a Lewis acid catalyst:
  • In Friedel−Crafts reactions.
  • In the carboxymethylation of alcohols in the presence of dimethyl carbonate.
  • To synthesize a porous organic polymer with hydroxyquinoline via polymerization reaction between perylene, 8-hydroxyquinoline, and chloroform.

It is also used in combination with NaI or KI in acetonitrile for varieties organic transformations such as Claisen rearrangement of aromatic alcohols, selective dealkylation aliphatic methyl ether, and chemoselective C−O bond cleavage of esters, acetals, ethers, and oxathiolanes.

Linkage

Replaces: AX0685-2; AX0685

Analysis Note

Assay (complexometric): ≥ 98.0 %
Identity (ICP-OES): passes test

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014,EUH071

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Aluminium chloride-potassium iodide-acetonitrile system: A mild reagent system for aromatic claisen rearrangement at ambient temperature
Bhattacharyya NK, et al.
Journal of the Indian Chemical Society, 98(2), 100024-100024 (2021)
A covalent triazine-based framework from tetraphenylthiophene and 2, 4, 6-trichloro-1, 3, 5-triazine motifs for sensing o-nitrophenol and effective I 2 uptake
Geng T, et al.
Polym. Chem., 9(6), 777-784 (2018)
Single-step synthesis of novel chloroaluminate ionic liquid for green Friedel-Crafts alkylation reaction
Sakhalkar M, et al.
Clean Technologies and Environmental Policy, 22(1), 59-71 (2020)
Constructing porous organic polymer with hydroxyquinoline as electrochemical-active unit for high-performance supercapacitor
Chen J, et al.
Polymer, 162, 43-49 (2019)
DFT and experimental analysis of aluminium chloride as a Lewis acid proton carrier catalyst for dimethyl carbonate carboxymethylation of alcohols
Jin Saimeng, et al.
Catalysis Science & Technology, 7(20), 4859-4865 (2017)

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