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343714

Sigma-Aldrich

Dichlorotris(1,10-phenanthroline)ruthenium(II) hydrate

98%

Synonym(s):

Tris(1,10-phenanthroline)ruthenium(II) chloride hydrate

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About This Item

Empirical Formula (Hill Notation):
C36H24Cl2N6Ru · xH2O
CAS Number:
Molecular Weight:
712.59 (anhydrous basis)
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Assay

98%

form

solid

reaction suitability

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

SMILES string

O.Cl[Ru]Cl.c1cnc2c(c1)ccc3cccnc23.c4cnc5c(c4)ccc6cccnc56.c7cnc8c(c7)ccc9cccnc89

InChI

1S/3C12H8N2.2ClH.H2O.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;;/h3*1-8H;2*1H;1H2;/q;;;;;;+2/p-2

InChI key

WGNGRGQLNAWTJI-UHFFFAOYSA-L

General description

The oxygen sensitivity and phototoxicity of [Ru(Phen)] in chicken embryo chorioallantoic membrane was investigated.

Application

Fluorescence quenching of dichloro(tris-1,10-phenanthroline) ruthenium (II) hydrate is is triggered by oxygen.1 (Ru(phen)3Cl2 may be used to imprint mesoporous molecular sieves (SBA-15).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

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Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Molecular imprinting of mesoporous SBA-15 with chiral ruthenium complexes.
Coutinho D,et al
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association null
Jianfeng Zhang et al.
Polymers, 12(4) (2020-04-25)
A cost-effective, simple, and time-saving method to fabricate mono-dispersed periodic microsphere structures on substrates with patterned sites is very meaningful due to their significance on various biological studies. Herein, a simple and facile method to fabricate mono-dispersed microsphere arrays on
Molecular imprinting of mesoporous SBA-15 with chiral ruthenium complexes.
Coutinho D,et al
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 249-255 null
In vivo measurement of tissue oxygenation by time-resolved luminescence spectroscopy: advantageous properties of dichlorotris (1, 10-phenanthroline)-ruthenium (II) hydrate.
Huntosova V, et al.
Journal of Biomedical Optics null
Oxygen sensor based on the fluorescence quenching of a ruthenium complex immobilized in a biocompatible poly (ethylene glycol) hydrogel.
O' Neal DP, et al.
Sensors, 728-734 null

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