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Sigma-Aldrich

Cobalt(II) phthalocyanine

β-form, Dye content 97 %

Synonym(s):

Cobaltous phthalocyaninate, PcCo, Phthalocyanine cobalt(II) salt

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About This Item

Empirical Formula (Hill Notation):
C32H16CoN8
CAS Number:
3317-67-7
Molecular Weight:
571.46
Beilstein:
4121847
EC Number:
222-012-7
MDL number:
MFCD00010718
UNSPSC Code:
12352103
PubChem Substance ID:
24858616
NACRES:
NA.23

form

powder

composition

Dye content, 97%

SMILES string

[Co]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Co/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI key

MPMSMUBQXQALQI-UHFFFAOYSA-N

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General description

Cobalt(II) phthalocyanine (CoPC )is a metallopthalocyanine.

Application

Self assembled molecules of CoPC were deposited on epitaxial graphene. CoPC may be used to develop carbon black based electrocatalysts. CoPC modified carbon paste may be used as indicators for electrocatalytic amperometric measurements. ZnO impregnated with CoPC may be used as a sensitizer to determine the photodegradation of cyanide in aqueous suspension. CoPC catalysed aerobic regenerations of aldehydes and ketones have been investigated. CoPC may also be used as an end capping agent of a hyperbranched poly(aryl ether ketone) to be used for oxidative decomposition of 2,4,6,-trichlorophenol.

Pictograms

Health hazard
GHS08

Signal Word

Warning

Hazard Statements

H351

Precautionary Statements

P201 - P308 + P313

Hazard Classifications

Carc. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Kevin C Honeychurch et al.
Analytical and bioanalytical chemistry, 396(8), 3103-3111 (2010-03-06)
Cobalt phthalocyanine-modified screen-printed carbon electrodes (CoPC-SPCEs) have been investigated as disposable sensors for the measurement of citric acid. The analyte was found to undergo an electrocatalytic oxidation process involving the Co(2+)/Co(3+) redox couple. Calibration plots were found to be linear
L M P C Centurion et al.
Journal of nanoscience and nanotechnology, 12(3), 2399-2405 (2012-07-05)
In the field of organic thin films, manipulation at the nanoscale can be obtained by immobilization of different materials on platforms designed to enhance a specific property via the layer-by-layer technique. In this paper we describe the fabrication of nanostructured
A I Medvedev et al.
Tsitologiia, 54(5), 417-420 (2012-07-26)
High-molecular-weight DNA fragments are the markers of the early stage of apoptosis induced in eukaryotic cells by cytotoxins of different nature. The dynamics of the development of large-scale DNA fragmentation in K-562 leukemia cells by the action of the antitumor
Pan Li et al.
ACS applied materials & interfaces, 5(6), 2255-2260 (2013-03-05)
In this work, the soluble cobalt phthalocyanine functionalized multiwalled carbon nanotubes (MWCNTs) are synthesized by π-π stacking interaction between tetrakis (3-trifluoromethylphenoxy) phthalocyaninato cobalt(II) (CoPcF) complex and MWCNTs. The physical properties of CoPcF-MWCNTs hybrids are evaluated using spectroscopy (UV-vis, XPS, and
Huazhang Zhao et al.
Environmental science & technology, 46(9), 5198-5204 (2012-04-06)
Electrochemical reduction of carbon dioxide (CO(2)) to useful chemical materials is of great significance to the virtuous cycle of CO(2). However, some problems such as high overpotential, high applied voltage, and high energy consumption exist in the course of the
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