255645

Cesium carbonate

99.995% trace metals basis

• Synonym(s): Carbonic acid dicesium
• Linear Formula: Cs₂CO₃
• CAS Number: 534-17-8
• Molecular Weight: 325.82
• Beilstein: 4546405
• EC Number: 208-591-9
• MDL number: MFCD00010957
• UNSPSC Code: 26111700
• PubChem Substance ID: 24855470
• NACRES: NA.23

Properties

• Assay: 99.995% trace metals basis
• form: powder
• mp: 610 °C (dec.) (lit.)
• application(s): battery manufacturing
• SMILES string: [Cs+].[Cs+].[O-]C([O-])=O
• InChI: 1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
• InChI key: FJDQFPXHSGXQBY-UHFFFAOYSA-L

Description

General description

Cesium carbonate is a mild inorganic base widely used inelectroluminescent devices and organic synthesis. Due to its excellent electroninjection capability, it is used as an interface modifying material in organiclight-emitting diodes (OLED), organic field effect transistors (OFET), organicsolar cells (OSCs), and perovskite solar cells.

Application

Cesium carbonate can be used as:

• A cathode buffer layer to enhance device stability and power conversion efficiency in polymer solar cells.
• A precursor to prepare alkali-based electrolyte for selective reduction of CO₂ by electrocatalysis.
• A base in many organic transformations such as C, N, O alkylation, and arylation reactions.

Promotes the efficient O-alkylation of alcohols to form mixed alkyl carbonates.

Safety Information

• Pictograms: GHS08,GHS05
• Signal Word: Danger
• Hazard Statements: H318,H361f,H373
• Precautionary Statements: P202 - P260 - P280 - P305 + P351 + P338 - P308 + P313 - P405
• Hazard Classifications: Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral
• Target Organs: Kidney,Adrenal gland,Testes
• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves