555169
Poly[(m-phenylenevinylene)-co-(2,5-dioctoxy-p-phenylenevinylene)]
light-emitting polymer, predominantly trans
Synonym(s):
Poly(m -phenylenevinylene-co -2,5-dioctoxy-p -phenylenevinylene)
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solubility
chloroform: soluble 2 wt. %
λmax
402 nm
fluorescence
λex 405 nm; λem 452 nm in chloroform
General description
Poly[(m-phenylenevinylene)-co-(2,5-dioctoxy-p-phenylenevinylene)](PmPV) is a conjugated luminescent polymer with meta linked phenylene ring within the backbone. It has a good non-linear optical response and a high degree of crystallinity.
Semi-conjugated, light-emitting polymer.
Application
PmPV in combination with carbon nanotubes (CNTs), graphene and fullerene forms stable nanocomposites with enhanced electrical and mechanical properties. These composites can potentially be used as semiconducting materials for a variety of electronic applications.
Used in the purification of carbon nanotubes.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Chemically derived, ultrasmooth graphene nanoribbon semiconductors
Li X, et al.
Science, 319(5867), 1229-1232 (2008)
Effective stimulated emission and excited-state absorption cross-section spectra of poly (m-phenylenevinylene-co-2, 5-dioctoxy-p-phenylenevinylene) and t, t?-didecycloxy-II-distyrylbenzene
Holzer W, et al.
Chemical Physics, 224(2-3), 315-326 (1997)
Synthesis and optical properties of phenylene-vinylene copolymers
Davey AP, et al.
Synthetic Metals, 103(1-3), 2478-2479 (1999)
Amphiphilic poly (p-phenylene)-driven multiscale assembly of fullerenes to nanowhiskers
Nurmawati MH, et al.
ACS Nano, 2(7), 1429-1436 (2008)
Direct Observation of the Ordering and Molecular Folding of Poly [(m-phenylenevinylene)-co-(2, 5-dioctoxy-p-phenylenevinylene)]
Lei SB, et al.
Advanced Materials, 16(9-10), 828-831 (2004)
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