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309281

Sigma-Aldrich

Iron(III) perchlorate hydrate

crystalline

Synonym(s):

Perchloric acid iron(III) salt hydrate

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About This Item

Linear Formula:
Fe(ClO4)3 · xH2O
CAS Number:
15201-61-3
Molecular Weight:
354.20 (anhydrous basis)
EC Number:
236-908-0
MDL number:
MFCD00149705
UNSPSC Code:
12352000
PubChem Substance ID:
24858725
NACRES:
NA.22

form

crystalline

reaction suitability

reagent type: oxidant

impurities

<0.10% chloride

color

yellow

SMILES string

[Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3

InChI key

PFPIMAZLJXJVAN-UHFFFAOYSA-K

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Application

Catalyst for synthesis of:
  • Fullerene-fused lactones
  • α-Carbonyl furans via one-pot cyclization
  • Fullerodioxolanes via heterocyclization
  • Dialylated indoles via double alkylation
  • Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization
Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution.

It can be used as a catalyst for synthesis of:
  • Fullerene-fused lactones
  • α-Carbonyl furans via one-pot cyclization
  • Fullerodioxolanes via heterocyclization
  • Fulleroxazolidines
  • Dialylated indoles via double alkylation
  • Aryl esters via oxidative esterification

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Pictograms

Flame over circleExclamation mark
GHS03,GHS07

Signal Word

Danger

Hazard Statements

H272,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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A facile access to [60] fullerene-fused 1, 3-dioxolanes: Reaction of [60] fullerene with aldehydes/ketones promoted by ferric perchlorate.
Li FB, et al
Organic Letters, 12(14), 3258-3261 (2010)
Iron salt-catalyzed cascade type one-pot double alkylation of indole with vinyl ketones.
Kobayashi JK, et al.
Tetrahedron, 66(22), 3917-3922 (2010)
Diverse redox chemistry of photo/ferrioxalate system.
Wang Z, et al.
Royal Society of Chemistry Advances, 4(84), 44654-44658 (2014)
Ferric Perchlorate Promoted Reaction of [60] Fullerene with N-Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines.
Liu TX, et al.
The Journal of Organic Chemistry, 80(24), 11986-11992 (2015)
Iron-Catalyzed Domino Process for the Synthesis of ?-Carbonyl Furan Derivatives via One-Pot Cyclization Reaction.
Jiang H
The Journal of Organic Chemistry, 75(15), 5347-5350 (2010)
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