93874

Fluroxypyr

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Synonym(s): 2-[(4-Amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic acid, 4-Amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid
• Empirical Formula (Hill Notation): C₇H₅Cl₂FN₂O₃
• CAS Number: 69377-81-7
• Molecular Weight: 255.03
• Beilstein: 7136185
• MDL number: MFCD01311822
• UNSPSC Code: 41116107
• NACRES: NA.24

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 100
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• storage temp.: 2-8°C
• SMILES string: Nc1c(Cl)c(F)nc(OCC(O)=O)c1Cl
• InChI: 1S/C7H5Cl2FN2O3/c8-3-5(11)4(9)7(12-6(3)10)15-1-2(13)14/h1H2,(H2,11,12)(H,13,14)
• InChI key: MEFQWPUMEMWTJP-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ. Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate. Download your certificate at: http://www.sigma-aldrich.com

Fluroxypyr is a systemic herbicide that belongs to the pyridine family and is widely used in crop fields for controlling the post-emergence broadleaf weeds. Fluroxypyr is applied in ester form and after uptake by the leaf, it is hydrolyzed to fluroxypyr acid, which is translocated rapidly to other parts of plants. It induces auxin-like responses, disrupts the key metabolic process, and causes lethal symptoms in plants

The Acceptable Daily Intake (ADI) and an Acceptable Operator Exposure Level (AOEL) for Fluroxypyr has been defined at 0.8 mg/kg body weight. Fluroxypyr is approved for use in European Union (EU) as per Regulation (EC) No 1107/2009. The maximum residue level (MRLs) for Fluroxypyr (sum of fluroxypyr, its salts, esters, and conjugates, expressed as fluroxypyr) has been set from 0.01 mg/kg to 2 mg/kg for products of plants and animal origin following Regulation (EU) 2021/1098.

Fluroxypyr has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques. The Fluroxypyr CRM may also find following uses:

• Evaluate the eco-toxicity of fluroxypyr to green algae, bioaccumulation, and degradation of fluroxypyr in Chlamydomonas reinhardtii, followed by investigation of its biological adaptation to fluroxypyr toxicity
• Study the effects of soil microbe, soil type, dissolved organic matter, temperature, soil moisture, and surfactant on fluroxypyr degradation in soils
• Study the photocatalytic degradation of herbicide fluroxypyr in aqueous suspension of TiO₂
• Investigate the adsorption and thermal desorption of the herbicide fluroxypyr on activated carbon fibers and cloth at different pH values
• Study the hydrolysis, aqueous photolysis, and soil degradation of fluroxypyr under laboratory conditions

Recommended products

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Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Hazard Statements: H412
• Precautionary Statements: P273 - P501
• Hazard Classifications: Aquatic Chronic 3
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable