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60716

Sigma-Aldrich

5-Keto-D-gluconic acid potassium salt

≥98.0% (TLC)

Synonym(s):

D-Xylo-5-hexulofuranosonic acid potassium salt

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About This Item

Empirical Formula (Hill Notation):
C6H9KO7
CAS Number:
Molecular Weight:
232.23
Beilstein:
3919618
MDL number:
UNSPSC Code:
12352201

Assay

≥98.0% (TLC)

impurities

~7% water

solubility

H2O: 50 mg/mL, clear, colorless

storage temp.

2-8°C

SMILES string

[K+].OCC(=O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O

InChI

1S/C6H10O7.K/c7-1-2(8)3(9)4(10)5(11)6(12)13;/h3-5,7,9-11H,1H2,(H,12,13);/q;+1/p-1/t3-,4+,5-;/m1./s1

InChI key

GSFHMOMWXNDPMM-YMDUGQBDSA-M

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Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Ittipon Saichana et al.
Applied and environmental microbiology, 75(13), 4240-4247 (2009-05-05)
We isolated thermotolerant Gluconobacter strains that are able to produce 5-keto-d-gluconic acid (5KGA) at 37 degrees C, a temperature at which regular mesophilic 5KGA-producing strains showed much less growth and 5KGA production. The thermotolerant strains produced 2KGA as the major
Marcel Merfort et al.
Applied microbiology and biotechnology, 73(2), 443-451 (2006-07-06)
Gluconobacter oxydans DSM 2343 is known to catalyze the oxidation of glucose to gluconic acid, and subsequently, to 2-keto-D-gluconic acid (2-KGA) and 5-keto-D-gluconic acid (5-KGA), by membrane-bound and soluble dehydrogenases. In G. oxydans MF1, in which the membrane-bound gluconate-2-dehydrogenase complex
Tuomas Salusjärvi et al.
Applied microbiology and biotechnology, 66(6), 664-667 (2004-11-27)
The chromosomal locus NP_636946 of Xanthomonas campestris DSM 3586 (ATCC 33913) which was earlier presumed to encode a quinoprotein glucose dehydrogenase has been cloned, expressed in Escherichia coli and the recombinant enzyme has been characterised. It was found to have
Marcel Merfort et al.
Biotechnology journal, 1(5), 556-563 (2006-08-08)
Gluconobacter oxydans DSM 2343 (ATCC 621H)catalyzes the oxidation of glucose to gluconic acid and subsequently to 5-keto-D-gluconic acid (5-KGA), a precursor of the industrially important L-(+)-tartaric acid. To further increase 5-KGA production in G. oxydans, the mutant strain MF1 was
Kazunobu Matsushita et al.
Applied and environmental microbiology, 69(4), 1959-1966 (2003-04-05)
Acetic acid bacteria, especially Gluconobacter species, have been known to catalyze the extensive oxidation of sugar alcohols (polyols) such as D-mannitol, glycerol, D-sorbitol, and so on. Gluconobacter species also oxidize sugars and sugar acids and uniquely accumulate two different keto-D-gluconates

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