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02553

Sigma-Aldrich

Phosphomolybdic acid solution

ready-to-use spray and plunge reagent, for chromatography

Synonym(s):

Molybdophosphoric acid

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About This Item

Linear Formula:
H3[P(Mo3O10)4]
CAS Number:
12026-57-2
Molecular Weight:
1825.25
MDL number:
MFCD00011341
UNSPSC Code:
12171500
PubChem Substance ID:
329747454
NACRES:
NA.47

grade

for chromatography

Quality Level

100

form

liquid

reaction suitability

reagent type: oxidant

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O

InChI

1S/12Mo.H3O4P.36O/c;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;(H3,1,2,3,4);;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;

InChI key

DHRLEVQXOMLTIM-UHFFFAOYSA-N

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General description

Phosphomolybdic acid solution (PMA), a ready-to-use spray solution is a component of Masson′s trichrome stain. It functions as a mordant, forming a bridge between the substrate and the primary dye.

Application

Phosphomolybdic acid solution is a ready-to-use spray for the visualization of steroids, alkaloids, antioxidants, and terpenes resolved by thin-layer chromatography (TLC) and high-performance TLC (HPTLC).

Signal Word

Danger

Hazard Statements

H225,H272,H314,H336

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Ox. Liq. 3 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

53.6 °F - closed cup

Flash Point(C)

12.0 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL4921
BCCJ4961
BCCG8122
BCCC8408
BCBX3796

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B Simonovska et al.
Journal of chromatography. A, 903(1-2), 219-225 (2001-01-12)
A high-performance thin-layer chromatographic (HPTLC) method for the determination of the two main potato glycoalkaloids, alpha-chaconine and alpha-solanine, in different parts of the potato plant, is described. Samples were extracted with diluted aqueous acetic acid containing the ion-pairing reagent 1-pentanesulfonic
Oleg Zui et al.
Talanta, 78(3), 1185-1189 (2009-03-10)
Interaction of luminol with phosphomolybdic, phosphovanadomolybdic and silicomolybdic acids was studied by examination of chemiluminescence spectra, measurement of ESR spectra, investigation of reaction order, and elucidation of inhibition effects. A scheme of the reaction mechanism is proposed.
Paweł K Zarzycki et al.
Analytica chimica acta, 688(2), 168-174 (2011-02-22)
The main goal of present paper is to demonstrate the separation and detection capability of micro-TLC technique involving simple one step liquid extraction protocols of complex materials without multi-steps sample pre-purification. In the present studies target components (cyanobacteria pigments, lipids
Dawei Fan et al.
Journal of colloid and interface science, 351(1), 151-155 (2010-08-19)
Hybrid films composed of oppositely charged Keggin-type 12-molybdophosphoric acid H(3)PMo(12)O(40).nH(2)O (PMo(12)) and water-soluble cationic meso-tetra (N-methyl-4-pyridyl) porphinetetratosylate (TMPyP) were fabricated onto silicon and ITO substrates by a layer-by-layer (LbL) self-assembly technique. The LbL films were characterized by UV-vis spectroscopy, X-ray
Juan Feng et al.
Analytical biochemistry, 409(1), 144-149 (2010-10-26)
The classical malachite green (MLG) assay of phosphate, which added MLG after molybdate to the acidified reaction solutions of phosphate, tolerated interference from papaverine, sildenafil, and some similar hydrophobic amines. Resonance Rayleigh scattering signals, the alleviation of interference by poly(vinyl
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