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ALD00615

Sigma-Aldrich

Ethyl (S,E)-2-((mesitylsulfinyl)imino)acetate

≥95%

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About This Item

Empirical Formula (Hill Notation):
C13H17NO3S
CAS Number:
Molecular Weight:
267.34
NACRES:
NA.22

Quality Level

Assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation

storage temp.

−20°C

Application

Ethyl (S,E)-2-((mesitylsulfinyl)imino)acetate is a chiral glyoxylate-derived sulfinimine reagent used for the synthesis of optically pure amino acids through a decarboxylative radical cross-coupling reaction.

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Shengyang Ni et al.
Angewandte Chemie (International ed. in English), 57(44), 14560-14565 (2018-09-14)
The direct union of primary, secondary, and tertiary carboxylic acids with a chiral glyoxylate-derived sulfinimine provides rapid access into a variety of enantiomerically pure α-amino acids (>85 examples). Characterized by operational simplicity, this radical-based reaction enables the modular assembly of

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