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930857

Sigma-Aldrich

Ni(bpy)Cl2

greener alternative

Synonym(s):

[Bipyridine]nickel(II) dichloride

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100 MG
NOK 962.00
500 MG
NOK 2,990.00

NOK 962.00


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100 MG
NOK 962.00
500 MG
NOK 2,990.00

About This Item

Empirical Formula (Hill Notation):
C10H8Cl2N2Ni
CAS Number:
Molecular Weight:
285.78
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.21

NOK 962.00


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form

powder

Quality Level

greener alternative product characteristics

Catalysis
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Greener Alternative Product

greener alternative category

storage temp.

−20°C

SMILES string

Cl[Ni]1([N]2=CC=CC=C2C3=CC=CC=[N]31)Cl

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ni(bpy)Cl2 is a nickel catalyst used for a variety of cross-coupling reactions.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Alexis L Gabbey et al.
Organic letters, 24(17), 3173-3178 (2022-04-27)
The transition-metal-catalyzed α-arylation of secondary amides remains a synthetic challenge due to the presence of a free N-H bond. We report a strategy to synthesize secondary α-aryl amides via a Ni-catalyzed reductive arylation of redox-active N-hydroxyphthalimide (NHP) esters of malonic

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