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905321

Sigma-Aldrich

Rh2(R-TCPTAD)4

Synonym(s):

Davies dirhodium catalyst

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About This Item

Empirical Formula (Hill Notation):
C80H64Cl16N4O16Rh2
CAS Number:
2223621-11-0
Molecular Weight:
2110.44
UNSPSC Code:
12352101
NACRES:
NA.22

form

powder, crystals or chunks

Related Categories

Application

This dirhodium catalyst developed by the Davies lab can form C-C bonds at the most accessible tertiary C-H position with control of both regioselectivity and absolute configuration.

Other Notes

Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds

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Description
Pricing

905291

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905313

Rh2(S-TCPTAD)4

905348

Rh2(R-p-Ph-TPCP)4

905259

Rh2(S-PTAD)4

905356

Rh2(R-PTAD)4

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Kuangbiao Liao et al.
Nature, 551(7682), 609-613 (2017-11-21)
The synthesis of complex organic compounds usually relies on controlling the reactions of the functional groups. In recent years, it has become possible to carry out reactions directly on the C-H bonds, previously considered to be unreactive. One of the

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