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Key Documents

771759

Sigma-Aldrich

2-Methylpyridine borane complex solution

0.5 M in dichloromethane

Synonym(s):

2-Picoline borane complex solution, 2-Picoline borane complex

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About This Item

Linear Formula:
C6H7N · BH3
CAS Number:
Molecular Weight:
106.96
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

form

liquid

reaction suitability

reagent type: reductant

concentration

0.5 M in dichloromethane

mp

44-46 °C (lit.)

density

1.297 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[BH3-][n+]1ccccc1C

InChI

1S/C6H10BN/c1-6-4-2-3-5-8(6)7/h2-5H,1,7H3

InChI key

JWXUMNOOAYRPKH-UHFFFAOYSA-N

Application

  • Environmentally benign reducing agent

Reactant for:
  • Reductive amination
  • N-Benzyl-protection of amino acid derivatives by reductive alkylation
  • Reductive alkoxyamination

Signal Word

Danger

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

Target Organs

Central nervous system

WGK

WGK 3


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