![Bis[2-(2′-bromoisobutyryloxy)ethyl]disulfide](/deepweb/assets/sigmaaldrich/product/structures/154/479/8d52d6e3-59da-4e56-8d9e-41b636138ca6/640/8d52d6e3-59da-4e56-8d9e-41b636138ca6.png)
Pt is utilized in ATRP (Atom Transfer Radical Polymerization) applications.
733350
Bis[2-(2-bromoisobutyryloxy)undecyl] disulfide
97%
Synonym(s):
11,11′-Dithiobis[1-(2-bromo-2-methylpropionyloxy)undecane], DTBU
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500 MG
NOK 3,310.00
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500 MG
NOK 3,310.00
About This Item
Empirical Formula (Hill Notation):
C30H56Br2O4S2
CAS Number:
Molecular Weight:
704.70
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
97%
form
solid
solubility
1.500 at 20 °C
density
1.177 g/mL at 25 °C
SMILES string
CC(C)(Br)C(=O)OCCCCCCCCCCCSSCCCCCCCCCCCOC(=O)C(C)(C)Br
InChI
1S/C30H56Br2O4S2/c1-29(2,31)27(33)35-23-19-15-11-7-5-9-13-17-21-25-37-38-26-22-18-14-10-6-8-12-16-20-24-36-28(34)30(3,4)32/h5-26H2,1-4H3
InChI key
IEGYEGYUHSQEAZ-UHFFFAOYSA-N
Application
Atom transfer Radical Polymerisation (ATRP) initiator commonly used to functionalize noble metal surfaces, and in the preparation of polymer brushes and biodegradable hydrogels. Also may be used to introduce a temperature and light sensitive cleavable region into the polymer.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Rui Yatabe et al.
Sensors (Basel, Switzerland), 13(7), 9294-9304 (2013-07-24)
In this study, we modified a surface plasmon resonance immunosensor chip with a polymer using surface-initiated atom transfer polymerization (SI-ATRP) for the highly sensitive detection of 2,4,6-trinitrotoluene (TNT). To immobilize a TNT analogue on the polymer, mono-2-(methacryloyloxy)ethylsuccinate (MES), which has
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Chemical modifications on histones and DNA/RNA constitute a fundamental mechanism for epigenetic regulation. These modifications often function as docking marks to recruit or stabilize cognate "reader" proteins. So far, a platform for quantitative and high-throughput profiling of the epigenetic interactome
Articles
ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.
Protocols
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
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Can the disulfide initiator be immobilized on the surface of pure Pt? The product description indicates that it can be used to "functionalize noble metal surfaces," with gold being a typical example. Will this process also work for Pt?
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