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566950

Sigma-Aldrich

4-Bromobenzyl mercaptan

97%

Synonym(s):

(4-Bromophenyl)methanethiol, 4-Bromo-α-toluenethiol

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About This Item

Linear Formula:
BrC6H4CH2SH
CAS Number:
19552-10-4
Molecular Weight:
203.10
MDL number:
MFCD03701566
UNSPSC Code:
12352100
PubChem Substance ID:
24880335
NACRES:
NA.22

Assay

97%

mp

27-31 °C (lit.)

functional group

bromo
thiol

SMILES string

SCc1ccc(Br)cc1

InChI

1S/C7H7BrS/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2

InChI key

CUCKXDPCCYHFMQ-UHFFFAOYSA-N

Application

4-Bromobenzyl mercaptan may be used to synthesize 4-bromotoluene via desulfurization with molybdenum hexacarbonyl [Mo(CO)6] in tetrahydrofuran.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
03923BH
04328CE
12822BE
08005JD
03026TO

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Zhengyu Zhang et al.
Chemical research in toxicology, 33(7), 1761-1769 (2020-06-10)
Dioscorea bulbifera L. (DBL), a traditional Chinese medicine, is a well-known herb with hepatotoxicity, and the biochemical mechanisms of the toxic action remain unknown. Diosbulbin B (DSB), a major component of DBL, can induce severer liver injury which requires cytochrome
?Transition-metal promoted reactions. 12. Molybdenum hexacarbonyl-promoted reductive cleavage of the carbon-sulfur bond?
Luh YT and Wong SC
The Journal of Organic Chemistry, 50(25), 5413-5415 (1985)
Franziska Leipoldt et al.
Nature communications, 8(1), 1965-1965 (2017-12-08)
Metalloproteinase inhibitors often feature hydroxamate moieties to facilitate the chelation of metal ions in the catalytic center of target enzymes. Actinonin and matlystatins are  potent metalloproteinase inhibitors that comprise rare N-hydroxy-2-pentyl-succinamic acid warheads. Here we report the identification and characterization of their biosynthetic

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