547794

Tris[N,N-bis(trimethylsilyl)amide]neodymium(III)

97%

• Synonym(s): 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt
• Linear Formula: Nd(N(Si(CH₃)₃)₂)₃
• CAS Number: 148274-47-9
• Molecular Weight: 625.39
• MDL number: MFCD03427089
• UNSPSC Code: 12352300
• PubChem Substance ID: 24878980

Properties

• Assay: 97%
• form: solid
• reaction suitability: reagent type: catalyst; core: neodymium
• mp: 156-159 °C (lit.)
• SMILES string: C[Si](C)(C)N([Nd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/3C6H18NSi2.Nd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
• InChI key: LWKIKGQVWYVALF-UHFFFAOYSA-N

Description

Application

Reagent for synthesis of:

• Imidophosphinate complexes of lanthanides
• Neodymium methoxides containing thienyl substituents
• Phenylene-bridged binuclear organolanthanide complexes
• Near-infrared photoluminescent neodymium(III) complexes

Reagent for:

• Rare-earth metal carboxylate-based catalysts
• Regioselective C-H activation

Safety Information

• Pictograms: GHS02,GHS05
• Signal Word: Danger
• Hazard Statements: H228,H261,H314
• Precautionary Statements: P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
• Supplementary Hazards: EUH014
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 36.0 °F - closed cup
• Flash Point(C): 2.2 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves