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464309

Sigma-Aldrich

Methoxyperfluorobutane

99%, mixture of n- and iso-butyl isomers

Synonym(s):

Nonafluorobutyl methyl ether, HFE-7100, Methoxynonafluorobutane, Methoxyperfluorobutane, Nonafluoromethoxybutane

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100 ML
NOK 1,060.00
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NOK 3,150.00

NOK 1,060.00

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100 ML
NOK 1,060.00
500 ML
NOK 3,150.00

About This Item

Linear Formula:
CH3OCF2R, R = -CF2CF2CF3 or -CF(CF3)2
CAS Number:
163702-07-6
Molecular Weight:
250.06
Beilstein:
8768491
MDL number:
MFCD28505595
UNSPSC Code:
12352100
PubChem Substance ID:
24870162
NACRES:
NA.22

NOK 1,060.00

Please contact Customer Service for Availability
Request a Bulk Order

Quality Level

100

Assay

99%

refractive index

n20/D 1.3 (lit.)

bp

60 °C (lit.)

mp

−135 °C (lit.)

density

1.52 g/mL at 25 °C (lit.)

functional group

ether
fluoro

SMILES string

COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F.COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F

InChI

1S/2C5H3F9O/c1-15-5(13,14)3(8,9)2(6,7)4(10,11)12;1-15-5(13,14)2(6,3(7,8)9)4(10,11)12/h2*1H3

InChI key

OKIYQFLILPKULA-UHFFFAOYSA-N

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Application

Methoxyperfluorobutane can be used as a solvent:
  • In the synthesis of various aryl fluoride derivatives via electrophilic fluorination of aryl and heteroaryl Grignard reagents.[1]
  • In grafting of fluorinated diblock copolymers onto silica particles.[2]

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV5018
MKCT6159
MKCR3498
MKCS2177
MKCP6468

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Coating of silica particles by fluorinated diblock copolymers and use of the resultant silica for superamphiphobic surfaces
Grozea CM, et al.
Polymer, 64(12), 153-162 (2015)
Li-Hsin Han et al.
Langmuir : the ACS journal of surfaces and colloids, 26(9), 6108-6110 (2010-03-31)
Three-dimensional organic microfabrication, an emerging technology, faces the challenge of lacking a sacrificial agent (SA) to temporarily support the formation of microscale geometries, which can be removed after a microstructure is constructed. In this study, an ultradense oil-in-organofluorine colloidal emulsion
Niko Nicolasora et al.
Forensic science international, 288, 266-277 (2018-05-25)
This paper contains details of work carried out to identify the most effective processing conditions for the optimized 1,2-indandione/zn formulation developed for use under UK conditions. Using direct measurements of fluorescence taken from test spots of amino acids and eccrine
Efficient synthesis of aryl fluorides.
Pazhamalai Anbarasan et al.
Angewandte Chemie (International ed. in English), 49(12), 2219-2222 (2009-12-17)
Howard C Knachel et al.
Magnetic resonance in chemistry : MRC, 51(7), 407-413 (2013-05-25)
The 3M Company product Novec™ 71IPA DL, a mixture of methoxyperfluorobutane, methoxyperfluoroisobutane and 4.5 wt.% isopropyl alcohol, has been found to be very stable at ambient temperature, producing fluoride at the rate of ~1 ppm/year. Our earlier kinetic and theoretical studies have
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