33820
Dibenzyl sulfide
≥95.0% (HPLC)
Synonym(s):
Benzyl sulfide
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About This Item
Linear Formula:
(C6H5CH2)2S
CAS Number:
Molecular Weight:
214.33
Beilstein:
1911157
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥95.0% (HPLC)
form
solid
mp
44-47 °C (lit.)
SMILES string
C(SCc1ccccc1)c2ccccc2
InChI
1S/C14H14S/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10H,11-12H2
InChI key
LUFPJJNWMYZRQE-UHFFFAOYSA-N
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General description
Sulfur K-edge XANES spectra of dibenzyl sulfide has been measured. Adsorption modes of dibenzyl disulphide on bare and iron-coated silver in 0.5M HCl was studied by surface-enhanced Raman scattering (SERS) spectroscopy. Dibenzyl sulfide undergoes oxidation to dibenzyl sulfoxide by SiO2-HNO3/KBr.
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Robert Beck et al.
Dalton transactions (Cambridge, England : 2003), (37)(37), 4981-4983 (2008-09-20)
C-H activation through the coordination of a benzyl sulfide anchoring group with a C-S bond cleavage at a Co(v) center constitutes a regiospecific access to four- and five-membered metallacycles under mild conditions.
Jonathan D Van Hamme et al.
Applied and environmental microbiology, 69(2), 1320-1324 (2003-02-07)
Microbial metabolism of organosulfur compounds is of interest in the petroleum industry for in-field viscosity reduction and desulfurization. Here, dibenzyl sulfide (DBS) metabolism in white rot fungi was studied. Trametes trogii UAMH 8156, Trametes hirsuta UAMH 8165, Phanerochaete chrysosporium ATCC
Vered Heleg-Shabtai et al.
Advances in experimental medicine and biology, 733, 53-61 (2011-11-22)
The improvements in Raman instrumentation have led to the development of -portable, simple to operate, Raman instruments that can be used for on-site analysis of substances relevant for homeland security purposes such as chemical and biological warfare and explosives materials.Raman
B Lei et al.
Journal of bacteriology, 178(19), 5699-5705 (1996-10-01)
The oxidation of dibenzothiophene to dibenzothiophene sulfone has been linked to the enzyme encoded by the sox/dszC gene from Rhodococcus sp. strain IGTS8 (S. A. Denome, C. Oldfield, L. J. Nash, and K. D. Young, J. Bacteriol. 176:6707-6717, 1994; C.
Chemo and homoselective catalytic oxidation of sulfides to sulfoxides with supported nitric acid on silica gel and poly vinyl pyrrolidone (PVP) catalyzed by KBr and/or NaBr.
Zolfigol MA, et al.
Catalysis Communications, 9(8), 1739-1744 (2008)
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