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254991

Sigma-Aldrich

Trichlorofluoromethane

≥99.5%

Synonym(s):

CFC-11, Fluorotrichloromethane, Freon® 11

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About This Item

Linear Formula:
Cl3CF
CAS Number:
75-69-4
Molecular Weight:
137.37
Beilstein:
1732469
EC Number:
200-892-3
MDL number:
MFCD00000784
UNSPSC Code:
12352100
PubChem Substance ID:
24855278
NACRES:
NA.22

vapor density

5.04 (vs air)

vapor pressure

12.85 psi ( 20 °C)
39.17 psi ( 55 °C)

Assay

≥99.5%

form

liquid

refractive index

n20/D 1.3821 (lit.)

bp

23.7 °C (lit.)

mp

−111-−110 °C (lit.)

solubility

water: soluble 1 g/L

density

1.494 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

FC(Cl)(Cl)Cl

InChI

1S/CCl3F/c2-1(3,4)5

InChI key

CYRMSUTZVYGINF-UHFFFAOYSA-N

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General description

Rotational absorption spectrum for the ground state of trichlorofluoromethane (Freon-11) has been measured on the part per thousand levels by volume by time-resolved THz spectroscopy. Reductive dehalogenation of trichlorofluoromethane catalyzed by Methanobacterium barkeri has been reported.

Application

Please view www.aldrich.com/epaods regarding the EPA′s request for application information of Ozone Depleting Substances

Legal Information

Freon is a registered trademark of E. I. du Pont de Nemours and Company

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H420

Precautionary Statements

P502

Hazard Classifications

Ozone 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Dehalogenation of trichlorofluoromethane (CFC-11) by Methanosarcina barkeri.
Krone UE and Thauer RK.
FEMS Microbiology Letters, 90(2), 201-204 (1992)
Terahertz (THz) spectroscopy of Freon-11 (CCl3F, CFC-11) at room temperature.
Altan H, et al.
Chemical Physics Letters, 427(4), 241-245 (2006)
S Li et al.
Biochemistry, 32(36), 9355-9361 (1993-09-14)
Biological reductive dehalogenation reactions are important in environmental detoxification of organohalides. Only scarce information is available on the enzymology underlying these reactions. Cytochrome P450CAM with a known X-ray structure and well-studied oxygenase reaction cycle, has been studied for its ability
Yolanda Olivas et al.
Environmental toxicology and chemistry, 21(3), 493-499 (2002-03-07)
To determine the influence of redox potential on the reaction mechanism and to quantify kinetics of the dechlorination by digester sludge, the test compounds trichlorofluoromethane (CFCl3), carbon tetrachloride (CCl4), and chloroform (CHCl3) were incubated in the presence of sludge and
Konrad Stemmler et al.
Environmental science & technology, 41(4), 1145-1151 (2007-06-28)
HFC-365mfc (1,1,1,3,3-pentafluorobutane) is an industrial chemical used for polyurethane foam blowing. From early 2003, HFC-365mfc has been commercially produced as a substitute for HCFC-141b, whose use in Europe has been banned since January 2004. We describe the first detection of
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