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252387

Sigma-Aldrich

Pentafluoropropionic anhydride

99%

Synonym(s):

PFPA, Perfluoropropionic anhydride

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About This Item

Linear Formula:
(CF3CF2CO)2O
CAS Number:
356-42-3
Molecular Weight:
310.05
Beilstein:
1806446
EC Number:
206-604-2
MDL number:
MFCD00000429
UNSPSC Code:
12352100
PubChem Substance ID:
24855205
NACRES:
NA.22

Assay

99%

form

liquid

bp

69-70 °C/735 mmHg (lit.)

density

1.571 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F

InChI

1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16

InChI key

XETRHNFRKCNWAJ-UHFFFAOYSA-N

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Application

Pentafluoropropionic anhydride was used:
  • in preparation of halogenated derivatives of phenolic acids, required for determination of some biologically important acids in cerebrospinal fluid
  • as derivatization reagent in detection of 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain by GC-multiple ion detection
  • in simultaneous determination of the major metabolites of dopamine in rat striatum by gas-liquid chromatography

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

EUH014

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Derivatization and gas chromatographic determination of some biologically important acids in cerebrospinal fluid.
E Watson et al.
Analytical biochemistry, 59(2), 441-451 (1974-06-01)
M Kohno et al.
Biochemical and biophysical research communications, 140(1), 448-454 (1986-10-15)
This is the first report to identify 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain. The detection was performed by coupled gas chromatography - multiple ion detection, using heptafluorobutyric anhydride and pentafluoropropionic anhydride as derivatizing reagents. These amines
Simultaneous determination of 3,4-dihydroxyphenylacetic acid and homovanillic acid in milligram amounts of rat striatal tissue by gas-liquid chromatography.
E Watson et al.
Life sciences, 15(12), 2167-2178 (1974-12-15)
Y S Oh-Shin et al.
Journal of chromatography. A, 769(2), 285-291 (1997-05-09)
A rapid and simple gas chromatographic method for the simultaneous determination of malathion, parathion, fenitrothion, diazinon and carbaryl in drinking water is presented. A fused-silica SE-54 column was used for the separation of the insecticides and was split into two
G F Grinstead
Journal of analytical toxicology, 15(6), 293-298 (1991-11-01)
PFPA and acetic anhydride derivatives of morphine and codeine were evaluated with respect to stability, chromatography, potential for analytical interferences by other opiates, and suitability of major fragment ions for analysis by GC/MS with deuterated internal standards and selected ion
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