- Synthesis of arylketones by ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids.
Synthesis of arylketones by ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids.
Chemical communications (Cambridge, England) (2011-06-11)
Hong Li, Yuan Xu, Erbo Shi, Wei Wei, Xiangqiang Suo, Xiaobing Wan
PMID21660337
ABSTRACT
The first ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids is reported. Various aliphatic and aromatic aldehydes are transformed to the corresponding arylketones. A total of 31 examples with moderate to excellent yields are presented, together with the results of an initial mechanistic investigation.
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