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498734

Sigma-Aldrich

5-Hexenylzinc bromide solution

0.5 M in THF

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About This Item

Linear Formula:
H2C=CH(CH2)4ZnBr
CAS Number:
226570-65-6
Molecular Weight:
228.45
MDL number:
MFCD01311405
UNSPSC Code:
12352103
PubChem Substance ID:
24873219
NACRES:
NA.22

concentration

0.5 M in THF

density

0.978 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]CCCCC=C

InChI

1S/C6H11.BrH.Zn/c1-3-5-6-4-2;;/h3H,1-2,4-6H2;1H;/q;;+1/p-1

InChI key

UQWLQJPHSGOLLO-UHFFFAOYSA-M

Application

5-Hexenylzinc bromide can be used as a starting material in the synthesis of 3,6-bis[(cyclopentyl)methyl]phthalonitrile, a key intermediate in the preparation of octasubstituted phthalocyanines.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3 - Water-react 2

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup

Certificates of Analysis (COA)

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Phthalocyanines bearing bulky cycloalkylmethyl substituents on non-peripheral sites
Cammidge AN, et al.
Tetrahedron Letters, 50(37), 5254-5256 (2009)

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