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359297

Sigma-Aldrich

Sodium ethanethiolate

technical grade, 80%

Synonym(s):

Ethanethiol sodium salt, Ethyl mercaptan sodium salt

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About This Item

Linear Formula:
CH3CH2SNa
CAS Number:
Molecular Weight:
84.12
Beilstein:
3593647
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Assay

80%

SMILES string

CCS[Na]

InChI

1S/C2H6S.Na/c1-2-3;/h3H,2H2,1H3;/q;+1/p-1

InChI key

QJDUDPQVDAASMV-UHFFFAOYSA-M

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General description

Reaction of FeCl2 or FeCl3 with sodium ethanethiolate in N-methylformamide (NMF) has been evaluated. Reaction of sodium ethanethiolate with substituted 1,2-dithiole-3-thiones has been studied.

Application

Sodium ethanethiolate may be used in the equilibrium titrations in N-methylformamide of G-25 gel filtered (ox)-state FeMo cofactor [FeMoco(ox)] from Azotobacter vinelandii nitrogenase. It may be used in the synthesis of a series of hybrid compounds combining the pharmacophoric redox moieties of vitamin E and key features responsible for the antiarrhythmic properties of the class I antiarrhythmics procainamide and lidocaine.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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P Frank et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 6(7), 683-697 (2001-10-30)
Equilibrium titrations in N-methylformamide (NMF) of G-25 gel filtered (ox)-state FeMo cofactor [FeMoco(ox)] from Azotobacter vinelandii nitrogenase were carried out using sodium ethanethiolate and followed using UV/Vis absorption spectroscopy. For Fe-Moco(ox), a non-linear least squares (NLLSQ) fit to the data
Patrick Frank et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 10(4), 373-382 (2005-05-03)
The reaction of FeCl(2) or FeCl(3) with sodium ethanethiolate (SEt) in N-methylformamide (NMF) has been reevaluated to rectify a previous Fe(II) oxidation artifact. On titrating Fe(II) with EtS(-) concentrations up to 12 mol Eq, new features in the UV/vis spectrum
Maria Koufaki et al.
Bioorganic & medicinal chemistry, 11(23), 5209-5219 (2003-11-08)
We have synthesized a series of hybrid compounds combining the pharmacophoric redox moieties of vitamin E and key features responsible for the antiarrhythmic properties of the class I antiarrhythmics procainamide and lidocaine. Procainamide analogue (2a) and lidocaine analogues (14a) and
Reactivity of substituted 1, 2-dithiole-3-thiones with sodium ethanethiolate: a convenient route to a novel heterocycle.
Largeron M, et al.
Tetrahedron, 43(15), 3421-3428 (1987)
Piotr Borowski et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 86, 571-585 (2011-12-14)
Multi-parameter scaling techniques, such as Scaled Quantum Mechanical (SQM) force field [J. Am. Chem. Soc. 105 (1983) 7037-7047; J. Phys. Chem. A 102 (1998) 1412-1424] or Effective Scaling Frequency Factor (ESFF) [Chem. Phys. Lett. 446 (2007) 191-198; J. Mol. Spectrosc.

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