260924
Bis(cyclopentadienyl)niobium(IV) dichloride
95%
Synonym(s):
Di(cyclopentadienyl)niobium(IV) dichloride, Niobocene dichloride
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About This Item
Empirical Formula (Hill Notation):
C10H10Cl2Nb
CAS Number:
Molecular Weight:
294.00
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
Assay
95%
reaction suitability
core: niobium
reagent type: catalyst
SMILES string
Cl[Nb]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.2ClH.Nb/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key
CYMWZQTUXXEBCR-UHFFFAOYSA-L
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Application
Catalyst for:
- Chain growth in controlled polymerization reactions
- Reduction elimination reactions
- Olefin polymerization reactions
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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M M Harding et al.
Journal of medicinal chemistry, 39(25), 5012-5016 (1996-12-06)
The solution chemistry and interactions of niobocene dichloride, Cp2NbCl2, with nucleosides, nucleotides, and amino acids has been studied by 1H and 31P NMR spectroscopy. The 1H NMR spectrum of Cp2NbCl2 in 10% DMSO-d6/D2O contains two sharp singlets consistent with hydrolysis
G Mokdsi et al.
Journal of inorganic biochemistry, 86(2-3), 611-616 (2001-09-22)
The interaction of the antitumor active metallocene dihalides Cp(2)MCl(2) (M=Ti, Nb, Mo) and 1 equiv. of glutathione was studied by (1)H NMR spectroscopy at pD 2-7 in 4 mM NaCl solutions. No interaction between glutathione and titanocene dichloride was detected
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