Skip to Content
Merck
All Photos(3)

Documents

208248

Sigma-Aldrich

Aluminum acetylacetonate

98%

Synonym(s):

Al(acac)3, Aluminum 2,4-pentanedionate

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Linear Formula:
Al(C5H7O2)3
CAS Number:
13963-57-0
Molecular Weight:
324.31
Beilstein:
4157942
EC Number:
237-741-6
MDL number:
MFCD00000013
UNSPSC Code:
12352103
PubChem Substance ID:
24852500
NACRES:
NA.23

Assay

98%

form

solid

reaction suitability

core: aluminum

bp

315 °C (lit.)

mp

190-193 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

KILURZWTCGSYRE-LNTINUHCSA-K

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Alumunium acetylacetonate is insoluble in water but soluble in organic solvents. It reacts with alkalis, acids, water at elevated temperatures. It can be prepared by reacting AlCl3 and acetylacetonate.

Application

Alumunium acetylacetonate may be used:
  • to prepare transparent superhydrophobic boehmite and silica films by sublimation,
  • to deposit alumunium oxide films by chemical vapor deposition,
  • as a catalyst.

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H300,H315,H319,H335

Hazard Classifications

Acute Tox. 2 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

244.4 °F

Flash Point(C)

118 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Aluminum oxide thin films prepared by chemical vapor deposition from aluminum acetylacetonate
Maruyama T, et al.
Applied Physics Letters, 60(3), 322-323 (1992)
Preparation of transparent superhydrophobic boehmite and silica films by sublimation of aluminum acetylacetonate.
Nakajima A, et al.
Advanced Mat., 11(16), 1365-1368 (1999)
B Corain et al.
Biomedical and environmental sciences : BES, 1(3), 283-287 (1988-10-01)
Aluminum acetylacetonate was administered to New Zealand white rabbits as liposome preparations and was found to distribute approximately 1:1 between water and phosphatidylcholine dipalmitoyl vesicles. Biochemical monitoring proved that after 2 weeks of daily injection of 40 micrograms of Al(III)
M Favarato et al.
Brain research, 569(2), 330-335 (1992-01-13)
To determine the influence of the metal coordination sphere on the permeability of the blood-brain barrier (BBB), rats were injected intraperitoneally with aluminum lactate (Al(lact)3), aluminum acetylacetonate (Al(acac)3), aluminum maltolate (Al(malt)3) at pH 7.5, or with physiological saline. Two h
T Ohyashiki et al.
Biochimica et biophysica acta, 1389(2), 141-149 (1998-02-14)
In the present study, the efficacy of a lipophilic Al complex, aluminum acetylacetonate, as a stimulator of Fe2+-initiated lipid peroxidation in phospholipid liposomes was examined, and results were compared with those from the liposomes treated with AlCl3. The extent of
View All Related Papers

Articles

Continuous Flow Monomer Synthesis

Monomers for ophthalmic use aim for purity, reliability, and comfort, driving innovation for affordable contact lenses.

Nanowire Synthesis: From Top-Down to Bottom-Up

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service