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178985

Sigma-Aldrich

Borane trimethylamine complex

97%

Synonym(s):

NSC 10220, NSC 145941, NSC 53323, Trihydro(trimethylamine)boron, Trimethylamine borane

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About This Item

Linear Formula:
(CH3)3N · BH3
CAS Number:
Molecular Weight:
72.95
Beilstein:
3905060
EC Number:
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

reagent type: reductant

bp

172 °C (lit.)

mp

92-94 °C (lit.)

SMILES string

[BH3-][N+](C)(C)C

InChI

1S/C3H12BN/c1-5(2,3)4/h1-4H3

InChI key

KQVSXUGMDCAISO-UHFFFAOYSA-N

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Application

Reducing agent for the preparation of plate-type palladium-zinc oxide catalyst

Reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents

Catalyst for:
  • Regioselective reductive opening of benzylidene acetal glycosides
  • Polarity reversal

Used to study
  • Electrodeposition condition effects on magnetism of cobalt-iron magnetic films
  • Boron-nitrogen bond dissociation energies and physiological activities of boronated compounds
Stable, easy-to-handle source of borane for the reduction of ketones and Schiff bases and for the hydroboration of olefins.

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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The Journal of Organic Chemistry, 59, 705-705 (1994)
Analytical Chemistry, 66, 4283-4283 (1994)
Aldrichimica Acta, 6, 51-51 (1973)

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