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661376

Sigma-Aldrich

2,3-Diaminophenazine

90%

Synonym(s):

2,3-Phenazinediamine

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About This Item

Empirical Formula (Hill Notation):
C12H10N4
CAS Number:
655-86-7
Molecular Weight:
210.23
EC Number:
211-512-0
MDL number:
MFCD00160693
UNSPSC Code:
12352100
PubChem Substance ID:
24884527
NACRES:
NA.22

Assay

90%

form

solid

mp

>300 °C

SMILES string

Nc1cc2nc3ccccc3nc2cc1N

InChI

1S/C12H10N4/c13-7-5-11-12(6-8(7)14)16-10-4-2-1-3-9(10)15-11/h1-6H,13-14H2

InChI key

VZPGINJWPPHRLS-UHFFFAOYSA-N

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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T Watanabe et al.
Mutation research, 245(1), 15-22 (1990-09-01)
The mutagenicity of o- and m-phenylenediamine (PD) was remarkedly enhanced by oxidation; their major mutagenic oxidation products were 2,3- and 2,7-diaminophenazine, respectively. In order to evaluate the modulation effect of p-PD on the oxidation of m- or o-PD, p-PD and
G Grosa et al.
Xenobiotica; the fate of foreign compounds in biological systems, 34(4), 345-352 (2004-07-23)
1. The results of an in vitro study of the metabolism of benzofuroxan using either cytosolic or microsomal fractions obtained from rat liver are reported. 2. Benzofuroxan was incubated with an appropriate volume of cytosol or microsomal suspension; control incubations
T Watanabe et al.
Mutation research, 244(4), 303-308 (1990-08-01)
Four commercial oxidative-type hair dye formulations, A, B, C, and D, were treated with hydrogen peroxide (H2O2) to simulate normal conditions of use, and the oxidized hair dyes were tested for their mutagenicity in Salmonella typhimurium TA98 in the presence
A M Sarrif et al.
Mutation research, 321(1-2), 43-56 (1994-04-01)
Benomyl (methyl [1-[(butylamino)carbonyl]-1H-benzimidazol-2- yl]carbamate) and its major metabolite carbendazim (methyl 2-benzimidazolecarbamate) are major agricultural systemic fungicides. These compounds inhibit fungal microtubular function and thereby cause nondisjunction of chromosomes at cell division. Several investigators have proposed that these compounds can also
E D Wagner et al.
Mutation research, 372(1), 65-74 (1996-11-11)
2,3-Diaminophenazine (DAP) and 2-amino-3-hydroxyphenazine (AHP) are products generated from oxidative-type phenylenediamine hair dyes and are also present in pesticide formulations as contaminants. Earlier studies demonstrated that DAP and AHP were mutagenic in Salmonella typhimurium strains after mammalian microsomal activation. Plant
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