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578177

Sigma-Aldrich

Polypyrrole

doped, conductivity 0.5-1.5 S/cm (pressed pellet, typical), extent of labeling: ~5 wt. % loading, coated on titanium dioxide

Synonym(s):

PPy

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About This Item

CAS Number:
30604-81-0
MDL number:
MFCD00284347
UNSPSC Code:
12352103
PubChem Substance ID:
24880912
NACRES:
NA.23

form

solid

contains

proprietary organic sulfonic acid as dopant

extent of labeling

~5 wt. % loading

solubility

H2O: insoluble
organic solvents: insoluble

InChI

1S/C4H5N/c1-2-4-5-3-1/h1-5H

InChI key

KAESVJOAVNADME-UHFFFAOYSA-N

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General description

Process up to at least 170°C in air. Process up to at least 270°C under nitrogen.Polypyrrole (PPy) is a conductive and highly stable polymer. It may be prepared by standard electrochemical technique. PPy may also be prepared by reacting β-napthalene sulfonic acid (NSA) and ammonium peroxo-disulphate in aqueous medium. The charges on the surfaces can be easily modified by doping the polymer during its synthesis. Solubility and conductivity measurements of PPy doped with camphor sulfonic and dodecyl benzene sulfonic acid has been reported.

Application

Conducting polymer.
Conductive additive for thermoplasitics and thermosets.

Packaging

Packaged in glass bottles

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Chemical Synthesis and Morphology of b?Naphthalene Sulfonic Acid-Doped Polypyrrole Micro/Nanotube.
Akinyeye R, et al.
Fullerenes, Nanotubes, and Carbon Nanostructures, 14 (2006)
Behzad Haghighi et al.
Colloids and surfaces. B, Biointerfaces, 103, 566-571 (2012-12-25)
An overoxidized polypyrrole (OOPPy) film was electrodeposited on a glassy carbon electrode (GCE) and the modified electrode (GCE/OOPPy) was then decorated with Au nanoparticles (nanoAu). Glucose oxidase was immobilized on the surface of nanoAu decorated OOPPy modified GCE to fabricate
Mingming Ma et al.
Science (New York, N.Y.), 339(6116), 186-189 (2013-01-12)
Here we describe the development of a water-responsive polymer film. Combining both a rigid matrix (polypyrrole) and a dynamic network (polyol-borate), strong and flexible polymer films were developed that can exchange water with the environment to induce film expansion and
Jie Shao et al.
Nanoscale, 5(4), 1460-1464 (2013-01-15)
In order to explore the potential application of sulfur in aqueous rechargeable batteries, core-shell sulfur-polypyrrole (S@PPy) composites were prepared through a novel one-pot and surfactant-free method. Sulfur exhibits a very high capacity of 473 mA h g(-1) and good cycling
Darren Svirskis et al.
Therapeutic delivery, 4(3), 307-313 (2013-02-28)
Intrinsically conducting polymers, such as polypyrrole (PPy), have been utilized for drug delivery purposes as drug release rates can be tuned by electrical stimulation. Electrical stimulation can be used to switch the redox state of PPy, subsequently changing the electrostatic
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